Hacimli Esterik Sübstitüentler İçeren Ftalosiyaninler
作者： Makbule Burkut Koçak , Ali Cihan , M. Kasım Şener
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摘要: Trikarbetoksietil ve naftil-malonik ester substitue ftalosiyaninler, dietil-(3,4-disiyanofenil)malonat’ in potasyum tuzu ile bromoasetikasit etil esteri 1-(klorometil)naftalin’in reaksiyonu sonucu hazirlanmis yeni iki farkli ftalonitril turevi ilgili metal tuzlarinin elde edilmistir. 2,9,17,23-Tetra-((1,1,2-(trikarbetoksi-etil))-ftalosiyaninato palladyum (II) ( 2 ) bilesiginin hidrolizi suksinik asit ftalosiyanin hazirlanmistir. Bu bilesigin su icerisinde pH’larda alinan UV-Vis spektrumunda pH » 12’ de monomerik dimerik turlerin her ikisinin oldugu 6’ da ise bir tek turun bulundugu gozlenmistir. Ayrica 1 DBU varliginda pentanol siklotetramerizasyonu transesterifikasyona ugramis metalsiz Sentezlenen bilesiklerin yapisi elementel analiz, FT-IR, UV-Vis, EI-MS, FAB-MS, H-NMR, 13 C-NMR yontemleri aydinlatilmistir. Anahtar Kelimeler: Ftalosiyanin, naftalen, ftalonitril, palladyum, kobalt, bakir.
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