Thermodynamic Study on the Surface Formation of the Mixture of Water and Ethanol

作者: Makoto Aratono , Takayuki Toyomasu , Masumi Villeneuve , Yorie Uchizono , Takanori Takiue

DOI: 10.1006/JCIS.1997.4929

关键词:

摘要: Abstract The formation of the water + ethanol mixture/air surface was studied by measuring tension as a function temperature and mole fraction in mixture. composition, entropy Δ s , energy u were evaluated adopting thermodynamic equations. It shown that enriched molecules compared with bulk solution. values examined closely estimating contribution from nonideal mixing solution at to . concluded is driven lower x 2 higher respectively, becomes more energetically favorable rising temperature.

参考文章(31)
Kinsi Motomura, Makoto Aratono, Norihiro Matubayasi, Ryohei Matuura, Thermodynamic studies on adsorption at interfaces Journal of Colloid and Interface Science. ,vol. 67, pp. 247- 254 ,(1978) , 10.1016/0021-9797(78)90009-7
Kinsi Motomura, Shin-Ichiro Iwanaga, Yoshiteru Hayami, Shozo Uryu, Ryohei Matuura, Thermodynamic studies on adsorption at interfaces: IV. Dodecylammonium chloride at water/air interface Journal of Colloid and Interface Science. ,vol. 80, pp. 32- 38 ,(1981) , 10.1016/0021-9797(81)90156-9
Kinsi Motomura, Hidemi Iyota, Norihiro Ikeda, Makoto Aratono, Thermodynamic studies on adsorption at interfaces Journal of Colloid and Interface Science. ,vol. 126, pp. 26- 36 ,(1988) , 10.1016/0021-9797(88)90095-1
Jacek Gliński, Guy Chavepeyer, Jean‐Karl Platten, Surface properties of diluted aqueous solutions of tert‐butyl alcohol Journal of Chemical Physics. ,vol. 102, pp. 2113- 2117 ,(1995) , 10.1063/1.468733
Makoto Aratono, Takanori Takiue, Norihiro Ikeda, Akira Nakamura, Kinsi Motomura, Thermodynamic study on the interface formation of water-long-chain alcohol systems The Journal of Physical Chemistry. ,vol. 96, pp. 9422- 9424 ,(1992) , 10.1021/J100202A066
J.H Clint, J.M Corkill, J.F Goodman, J.R Tate, Adsorption of n-alkanols at the Air/Aqueous Solution Interface Journal of Colloid and Interface Science. ,vol. 28, pp. 522- 530 ,(1968) , 10.1016/0021-9797(68)90085-4
Kazuko Mizuno, Yasue Miyashita, Yohji Shindo, Hideo Ogawa, NMR and FT-IR Studies of Hydrogen Bonds in Ethanol-Water Mixtures The Journal of Physical Chemistry. ,vol. 99, pp. 3225- 3228 ,(1995) , 10.1021/J100010A037