Preparation of thiol-ene based photo-crosslinked polymer as a potential phase change material
作者： Emre Baştürk , Duygu Yüksel Deniz , Memet Vezir Kahraman
DOI: 10.1016/J.MATCHEMPHYS.2016.04.064
关键词:
摘要: Abstract A series of novel photo-crosslinked thiol-ene based shape-stabilized phase change materials (PCMs) have been prepared for the use thermal energy storage applications. Four types formulations were with different fatty alcohols by adding di(trimethylolpropane) tetraacrylate (TMPTA), polyethylene (glycol) diacrylate (PEGDA) and pentaerythritoltetrakis(3-mercaptopropionate) (4-SH) in which we investigated their properties as PCMs. Fatty alcohols, 1-Octadecanol, 1-Eicosanol 1-Docosanol, added to formulations, respectively. The characterization tests performed ATR-FTIR spectroscopy. Phase behaviors performances using differential scanning calorimetry (DSC) thermogravimetric analysis system (TGA).The heating cycle enthalpy is measured between 27 43 J/g, freezing found 20 39 J/g. decomposition UV-cured PCMs started at 413 °C.The results indicate that possess good an applicable temperature range. With obtained these promise a great potential
sci-hub.se 参考文章(36)
Emre Baştürk, Burcu Oktay, Memet Vezir Kahraman, Dual-crosslinked thiol-ene/sol gel hybrid electrospun nanowires: preparation and characterization Journal of Polymer Research. ,vol. 22, pp. 133- ,(2015) , 10.1007/S10965-015-0784-5
Bingtao Tang, Lingjuan Wang, Yuanji Xu, Jinghai Xiu, Shufen Zhang, Hexadecanol/phase change polyurethane composite as form-stable phase change material for thermal energy storage Solar Energy Materials and Solar Cells. ,vol. 144, pp. 1- 6 ,(2016) , 10.1016/J.SOLMAT.2015.08.012
Duygu Yüksel Deniz, Memet Vezir Kahraman, Serap Erdem Kuruca, UV-reactive electrospinning of keratin/4-vinyl benzene boronic acid–hydroxyapatite/poly(vinyl alcohol) composite nanofibers Polymer Composites. ,vol. 38, pp. 1371- 1377 ,(2017) , 10.1002/PC.23703
Meenakshi Reddy, N. Nallusamy, Anjaneya Prasad, Hemachandra Reddy, Thermal energy storage system using phase change materials: Constant heat source Thermal Science. ,vol. 16, pp. 1097- 1104 ,(2012) , 10.2298/TSCI100520078R
Bogdan M. Diaconu, Szabolcs Varga, Armando C. Oliveira, Experimental assessment of heat storage properties and heat transfer characteristics of a phase change material slurry for air conditioning applications Applied Energy. ,vol. 87, pp. 620- 628 ,(2010) , 10.1016/J.APENERGY.2009.05.002
Seulgi Yu, Su-Gwang Jeong, Okyoung Chung, Sumin Kim, Bio-based PCM/carbon nanomaterials composites with enhanced thermal conductivity Solar Energy Materials and Solar Cells. ,vol. 120, pp. 549- 554 ,(2014) , 10.1016/J.SOLMAT.2013.09.037
Emrah Çakmakçı, Yusuf Mülazim, Memet Vezir Kahraman, Nilhan Kayaman Apohan, Flame retardant thiol-ene photocured coatings Reactive & Functional Polymers. ,vol. 71, pp. 36- 41 ,(2011) , 10.1016/J.REACTFUNCTPOLYM.2010.11.011
Fang Chen, Michael Wolcott, Polyethylene/paraffin binary composites for phase change material energy storage in building: A morphology, thermal properties, and paraffin leakage study Solar Energy Materials and Solar Cells. ,vol. 137, pp. 79- 85 ,(2015) , 10.1016/J.SOLMAT.2015.01.010
A. Abhat, Low temperature latent heat thermal energy storage: Heat storage materials Solar Energy. ,vol. 30, pp. 313- 332 ,(1983) , 10.1016/0038-092X(83)90186-X
Kunping Lin, Yinping Zhang, Xu Xu, Hongfa Di, Rui Yang, Penghua Qin, Experimental study of under-floor electric heating system with shape-stabilized PCM plates Energy and Buildings. ,vol. 37, pp. 215- 220 ,(2005) , 10.1016/J.ENBUILD.2004.06.017