Synthesis and catalytic activity of nickel(II) complexes of CNC pincer-type N-heterocyclic carbene ligands
作者： Shuchao Wang , Fang Ren , Yuping Qiu , Meiming Luo
DOI: 10.1016/J.JORGANCHEM.2015.04.019
关键词:
摘要: Abstract Air- and moisture-stable nickel(II) complexes 2a–c of CNC pincer-type N-heterocyclic carbene ligands have been prepared from the corresponding imidazolium salts by carbene–transfer reaction a silver-NHC complex with Ni(DME)Cl2 (DME = dimethoxylethane). Pincer are characterized mass NMR spectroscopy. The structure 2a is also identified X-ray diffraction analysis. has shown to be active catalyst for Suzuki coupling reactions.
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