First example of a 1:1 vanadium(IV)–citrate complex featuring the 2,2′-bipyridine co-ligand: Synthesis, X-ray crystal structure and DFT calculations

作者: Vida Jodaian , Masoud Mirzaei , Massimiliano Arca , M. Carla Aragoni , Vito Lippolis

DOI: 10.1016/J.ICA.2013.02.012

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摘要: An unprecedented 1:1:1 complex [VO(bipy)(cit [H] H)]·1.5H 2 O was obtained from the reaction of vanadium(III) chloride, 2,2′-bipyridine (bipy), and citric acid (cit [H] H 3 ) in methyl …

参考文章(53)
Stephen J. Lippard, Jeremy M. Berg, Principles of bioinorganic chemistry ,(1994)
Boyd Dempsey, E. P. Serjeant, Ionisation constants of organic acids in aqueous solution Pergamon Press. ,(1979)
Max C. Holthausen, Wolfram Koch, A Chemist's Guide to Density Functional Theory ,(2000)
G. Schaftenaar, J.H. Noordik, Molden: a pre- and post-processing program for molecular and electronic structures. Journal of Computer-aided Molecular Design. ,vol. 14, pp. 123- 134 ,(2000) , 10.1023/A:1008193805436
M. Carla Aragoni, Massimiliano Arca, Mario Caironi, Carla Denotti, Francesco A. Devillanova, Emanuela Grigiotti, Francesco Isaia, Franco Laschi, Vito Lippolis, Dario Natali, Luca Pala, Marco Sampietro, Piero Zanello, Monoreduced [M(R,R′timdt)2]− dithiolenes (M = Ni, Pd, Pt; R,R′timdt = disubstituted imidazolidine-2,4,5-trithione): solid state photoconducting properties in the third optical fiber window Chemical Communications. ,vol. 16, pp. 1882- 1883 ,(2004) , 10.1039/B406406B
Hiromu Sakurai, Yoshitane Kojima, Yutaka Yoshikawa, Kenji Kawabe, Hiroyuki Yasui, Antidiabetic vanadium(IV) and zinc(II) complexes Coordination Chemistry Reviews. ,vol. 226, pp. 187- 198 ,(2002) , 10.1016/S0010-8545(01)00447-7
M. Tsaramyrsi, M. Kaliva, A. Salifoglou, C. P. Raptopoulou, A. Terzis, V. Tangoulis, J. Giapintzakis, Vanadium(IV)-citrate complex interconversions in aqueous solutions. A pH-dependent synthetic, structural, spectroscopic, and magnetic study. Inorganic Chemistry. ,vol. 40, pp. 5772- 5779 ,(2001) , 10.1021/IC010276N
Natalie Banerji, Eric Gagnon, Pierre-Yves Morgantini, Sebastian Valouch, Ali Reza Mohebbi, Jung-Hwa Seo, Mario Leclerc, Alan J. Heeger, Breaking Down the Problem: Optical Transitions, Electronic Structure, and Photoconductivity in Conjugated Polymer PCDTBT and in Its Separate Building Blocks Journal of Physical Chemistry C. ,vol. 116, pp. 11456- 11469 ,(2012) , 10.1021/JP301639E
Murugesan Velayutham, Babu Varghese, Sankaran Subramanian, Magneto-Structural Correlation Studies of A Ferromagnetically Coupled Dinuclear Vanadium(IV) Complex. Single-Crystal EPR Study. Inorganic Chemistry. ,vol. 37, pp. 1336- 1340 ,(1998) , 10.1021/IC9707467
Jihong Liang, Mark Madden, Vinod K. Shah, Robert H. Burris, Citrate substitutes for homocitrate in nitrogenase of a nifV mutant of Klebsiella pneumoniae Biochemistry. ,vol. 29, pp. 8577- 8581 ,(1990) , 10.1021/BI00489A011