Highly (222)-oriented pyrochlore PZN-PT thin films prepared by pulsed laser deposition

作者: H. L. Han , A. Y. Liu , L. L. Wei , P. Wang , F. T. Lin

DOI: 10.1117/12.2053925

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摘要: ABSTRACT Highly (222)-oriented 90%Pb(Zn 1/3 Nb 2/3 )O 3 -10%PbTiO (abbreviated PZN–PT) thin films, about 550nm in thickness, have been successfully grown on (111)Pt/Ti/SiO 2 /Si substrate by pulsed laser deposition method. Pure pyrochlore phase with highly (222)-preferred orientation, determined X-ray diffraction, was formed the PZN–PT films when temperature of substrates is 550 ƒ&. FE -SEM investigation shows that surface appearance and cross section are smooth crack-free some dispersive spherical protrusions. The dielectric constant loss were measured using an impedance anal yzer (HP4194A). ( H r ) dissipation factor tan G at 1 kHz 205 0.03, respectively. Keywords: PZN-PT deposition, pyrochlore, 1. INTRODUCTION Perovskite (1-x)PZN-xPT single crystals exhibit very high permittivity > 3000), excellent coupling coefficients (k

参考文章(17)
Metin Ozgul, Koichi Takemura, Susan Trolier-McKinstry, Clive A. Randall, Polarization fatigue in Pb(Zn1/3Nb2/3)O3–PbTiO3 ferroelectric single crystals Journal of Applied Physics. ,vol. 89, pp. 5100- 5106 ,(2001) , 10.1063/1.1335819
X. H. Zhu, E. Defaÿ, A. Suhm, E. Fribourg-blanc, M. Aïd, Ultralow dielectric losses in pyrochlore films of the PbO–MgO–Nb2O5–TiO2 system Applied Physics Letters. ,vol. 94, pp. 122906- ,(2009) , 10.1063/1.3106107
Lingfei Ji, Yijian Jiang, Wei Wang, Zhenlong Yu, Enhancement of the dielectric permittivity of Ta2O5 ceramics by CO2 laser irradiation Applied Physics Letters. ,vol. 85, pp. 1577- 1579 ,(2004) , 10.1063/1.1784539
Graham K. Hubler, Douglas B. Chrisey, Pulsed laser deposition of thin films Pulsed Laser Deposition of Thin Films. pp. 1675- 1689 ,(2003) , 10.1201/NOE0750309608-90
Gregory K. L. Goh, X. Q. Han, Cheryl P. K. Liew, Christine S. S. Tay, Crystallinity and Orientation of Solution Deposited Anatase TiO2 Films Journal of The Electrochemical Society. ,vol. 152, ,(2005) , 10.1149/1.1943590
Huiqing Fan, Seung-Ho Lee, Chang-Bun Yoon, Gun-Tae Park, Jong-Jin Choi, Hyoun-Ee Kim, Perovskite structure development and electrical properties of PZN based thin films Journal of The European Ceramic Society. ,vol. 22, pp. 1699- 1704 ,(2002) , 10.1016/S0955-2219(01)00464-2
Yi Yang, Kyekyoon Kim, Hyungsoo Choi, Fabrication of perovskite-based Pb(Zn1/3Nb2/3)O3 (PZN) thin films using charged liquid cluster beam Thin Solid Films. ,vol. 396, pp. 97- 102 ,(2001) , 10.1016/S0040-6090(01)01236-6
Takamitsu Fujiu, Akira Tanaka, Tadashi Takenaka, Processing of Perovskite Pb(Zn<1/3Nb2/3)O3by Hot Isostatic Pressing and Its Dielectric Properties Japanese Journal of Applied Physics. ,vol. 30, pp. L298- L301 ,(1991) , 10.1143/JJAP.30.L298
Naoki Wakiya, Nobuo Ishizawa, Kazuo Shinozaki, Nobuyasu Mizutani, Thermal stability of Pb(Zn13Nb23)O3 (PZN) and consideration of stabilization conditions of perovskite type compounds Materials Research Bulletin. ,vol. 30, pp. 1121- 1131 ,(1995) , 10.1016/0025-5408(95)00102-6
Xiao-hong Du, Uma Belegundu, Kenji Uchino, Crystal Orientation Dependence of Piezoelectric Properties in Lead Zirconate Titanate : Theoretical Expectation for Thin Films Japanese Journal of Applied Physics. ,vol. 36, pp. 5580- 5587 ,(1997) , 10.1143/JJAP.36.5580