Homogeneous linewidths of single rotational lines in the ‘‘channel three’’ region of C6H6
作者： E. Riedle , H. J. Neusser
DOI: 10.1063/1.446533
关键词:
摘要: Homogeneous linewidths of single rotational lines have been measured in the ‘‘channel three’’ region C6H6. The necessary spectral resolution about 5 MHz and high sensitivity were achieved by Doppler‐free two‐photon spectroscopy within an external cavity setup. Linewidths produced intramolecular relaxation found to increase strongly with increasing J for K=0 constant vibrational energy Eexcess =3412 cm−1. This result together investigated structure highly resolved spectrum 1410120 band is a strong indication that Coriolis coupling plays important role redistribution process.
harvard.edu
scitation.org
aip.org
sci-hub.se 参考文章(19)
Пётр Петрович Лазарев, Handbuch der Radiologie Успехи физических наук. ,vol. 1, pp. 82- 83 ,(1918)
B. E. Forch, K. T. Chen, H. Saigusa, E. C. Lim, Coriolis effects on intramolecular vibrational relaxation: rotational contour dependence of pyrimidine fluorescence The Journal of Physical Chemistry. ,vol. 87, pp. 2280- 2282 ,(1983) , 10.1021/J100236A007
C. E. Otis, J. L. Knee, P. M. Johnson, Nonradiative processes in the channel three region of the S1 state of ultracold benzene The Journal of Physical Chemistry. ,vol. 14, pp. 2232- 2239 ,(1983) , 10.1021/J100235A037
J.H. Callomon, J.E. Parkin, R. Lopez-Delgado, Non-radiative relaxation of the excited à 1B2u state of benzene Chemical Physics Letters. ,vol. 13, pp. 125- 131 ,(1972) , 10.1016/0009-2614(72)80059-9
I. M. Mills, Coriolis interactions, intensity perturbations and potential functions in polyatomic molecules Pure and Applied Chemistry. ,vol. 11, pp. 325- 344 ,(1965) , 10.1351/PAC196511030325
Kenneth G. Spears, Stuart A. Rice, Study of the Lifetimes of Individual Vibronic States of the Isolated Benzene Molecule The Journal of Chemical Physics. ,vol. 55, pp. 5561- 5581 ,(1971) , 10.1063/1.1675724
Charles S. Parmenter, Vibrational energy flow within excited electronic states of large molecules The Journal of Physical Chemistry. ,vol. 86, pp. 1735- 1750 ,(1982) , 10.1021/J100207A001
Wan-Ü L. Brillet, A. Gallagher, Inert-gas collisional broadening and shifts of Rb Rydberg states Physical Review A. ,vol. 22, pp. 1012- 1017 ,(1980) , 10.1103/PHYSREVA.22.1012
F. Biraben, M. Bassini, B. Cagnac, Line-shapes in Doppler-free two-photon spectroscopy. The effect of finite transit time Journal De Physique. ,vol. 40, pp. 445- 455 ,(1979) , 10.1051/JPHYS:01979004005044500
C. S. Parmenter, B. Setzer, K. Y. Tang, Electronic energy transfer between single vibronic levels of C6H6 and C6D6 vapors The Journal of Chemical Physics. ,vol. 66, pp. 1317- 1323 ,(1977) , 10.1063/1.434026