Organometallic Oxides: Oxidation of the Cubane [(η-C5R5)Cr(μ3-O)]4 and the Structures and Magnetic Properties of the Salts {[(η-C5R5)Cr(μ3-O)]4}{tcnq} and {[(η-C5R5)Cr(μ3-O)]4}{BF4}
作者： Daryl P. Allen , Frank Bottomley , Robert W. Day , Andreas Decken , Victor Sanchez
DOI: 10.1021/OM001067Y
关键词:
摘要: Differential pulse and current voltammetry for the cubane-like clusters [(η-C5R5)Cr(μ3-O)]4 (R = H, Me; R5 H4Me) showed that [(η-C5H4Me)Cr(μ3-O)]4 [(η-C5Me5)Cr(μ3-O)]4 were oxidized to {[(η-C...
acs.org
sci-hub.se 参考文章(41)
L. M. Babcock, W. G. Klemperer, Highly condensed titanoxanes: synthesis of closo-(Cp*Ti)4O6 and its transformation to bicyclo-(Cp*Ti)4O5Cl2 with TiCl4 as an oxide acceptor reagent Inorganic Chemistry. ,vol. 28, pp. 2003- 2007 ,(1989) , 10.1021/IC00309A047
I.L. Eremenko, S.E. Nefedov, A.A. Pasynskii, B. Orazsakhatov, O.G. Ellert, Yu.T. Struchkov, A.I. Yanovsky, D.V. Zagorevsky, Antiferromagnetic complexes with the metalmetal bond: XIX. Influence of the nature of bridging ligands on geometry and magnetic properties of the metallotetrahedral clusters (MeC5H4)4Cr4(μ3-E)4 where E = O, S, Se☆ Journal of Organometallic Chemistry. ,vol. 368, pp. 185- 192 ,(1989) , 10.1016/0022-328X(89)85313-6
C. Sangregorio, T. Ohm, C. Paulsen, R. Sessoli, D. Gatteschi, QUANTUM TUNNELING OF THE MAGNETIZATION IN AN IRON CLUSTER NANOMAGNET Physical Review Letters. ,vol. 78, pp. 4645- 4648 ,(1997) , 10.1103/PHYSREVLETT.78.4645
James. Darkwa, John R. Lockemeyer, Peter D. W. Boyd, Thomas B. Rauchfuss, Arnold L. Rheingold, Synthetic, structural, and theoretical studies on the electron-deficient cubanes (RC5H4)4Ti4S4, (RC5H4)4V4S4, and [(RC5H4)4V4S4]+. Journal of the American Chemical Society. ,vol. 110, pp. 141- 149 ,(1988) , 10.1021/JA00209A023
Frank. Bottomley, Jinhua. Chen, Sarajane M. MacIntosh, Robert C. Thompson, Organometallic oxides: preparation and properties of the tetrahedral (Td) chromium cubane [(.eta.-C5(CH3)5)Cr(.mu.3-O)]4 and comparison with the D2 [(.eta.-C5H5)Cr(.mu.3-O)]4 and D2d [(.eta.-C5H4CH3)Cr(.mu.3-O)]4 Organometallics. ,vol. 10, pp. 906- 912 ,(1991) , 10.1021/OM00050A021
Frank Bottomley, Daniel E. Paez, Peter S. White, Preparation, properties and structures of the clusters hexakis(.mu.3-oxo)pentakis(.eta.5-cyclopentadienylvanadium), [(.eta.5-C5H5)5V5O6], and tetrakis(.mu.3-oxo)tetrakis(.eta.5-cyclopentadienylchromium), [(.eta.5-C5H5)4Cr4O4] Journal of the American Chemical Society. ,vol. 104, pp. 5651- 5657 ,(1982) , 10.1021/JA00385A016
R. E. Long, R. A. Sparks, K. N. Trueblood, The crystal and molecular structure of 7,7,8,8‐tetracyanoquinodimethane Acta Crystallographica. ,vol. 18, pp. 932- 939 ,(1965) , 10.1107/S0365110X65002256
Stephanie L. Castro, Ziming Sun, Craig M. Grant, John C. Bollinger, David N. Hendrickson, George Christou, Single-Molecule Magnets: Tetranuclear Vanadium(III) Complexes with a Butterfly Structure and an S ) 3 Ground State Journal of the American Chemical Society. ,vol. 120, pp. 2365- 2375 ,(1998) , 10.1021/JA9732439
Mamoru Shimoi, Asako Satoh, Hiroshi Ogino, Crystal Structures of Polymorphic [Fe4(η5-C5H5)4S4](PF6) Bulletin of the Chemical Society of Japan. ,vol. 64, pp. 11- 15 ,(1991) , 10.1246/BCSJ.64.11
John E. McGrady, Periodic trends in metal–metal bonding in cubane clusters, (C5H5)4M4E4 [M = Cr, Mo, E = O, S] Journal of The Chemical Society-dalton Transactions. pp. 1393- 1400 ,(1999) , 10.1039/A900660E