Ionic Components of Charge in the Electrical Double Layer

摘要: The rate of change with concentration the capacity electrical double layer on mercury has been measured. From this there have calculated Γ+, excess cations in layer, and Γ—, anions. latter subdivided into η—d, anions diffuse η—i, inner part layer. these data it also possible to evaluate ψ0, potential outer Helmholtz plane.It is found that fluoride ion remains unadsorbed at all potentials investigated, including anodic e.c.max. Other are strongly adsorbed (chemisorbed) when positively charged, sometimes even negatively charged. ``hump'' curves salts such as chloride, bromide, acetate, nitrate, be present C—, attributable alone. No chemisorption monatomic could detected.The kinetic...