The Role of the Cation in the Electrical Double Layer

作者: David C. Grahame

DOI: 10.1149/1.2778217

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摘要: The differential capacity of a number tenth‐normal aqueous solutions metallic chlorides has been measured as function potential. results are interpreted to mean that the solvent sheaths on positive and negative ions displaced approach interface. New explanations given for several well‐known phenomena connected with double layer. surface charge density integral non‐diffuse part electrical layer have calculated from these data. ratios capacities found unity at potentials where concentration cations within is minimum.

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