Copper behaviour in acid and alkaline brines—I kinetics of anodic dissolution in 0.5M NaCl and free-corrosion rates in the presence of oxygen
作者： G. Faita , G. Fiori , D. Salvadore
DOI: 10.1016/0010-938X(75)90005-0
关键词:
摘要: Abstract The behaviour of copper has been studied in 0·5M NaCl and at pH values ranging from 2 to 10. In acid solution the anodic dissolution reaction leads formation Cu+ ions which can either form soluble complexes or precipitate as solid CuCl depending on their surface concentration. former situation holds free-corrosion potential presence oxygen. alkaline range behaves, low current densities (i.e. potentials), same way it does solutions; more potentials a protective layer Cu2O is formed.
elsevier.com
sci-hub.se 参考文章(9)
Arthur Earl Martell, Lars Gunnar Sillén, Gerold Karl Schwarzenbach, Jannik Bjerrum, Stability constants of metal-ion complexes Published in <b>1964</b> in London by Chemical society. ,(1964)
John Price Riley, Introduction to marine chemistry ,(1971)
A. L. Bacarella, J. C. Griess, The Anodic Dissolution of Copper in Flowing Sodium Chloride Solutions Between 25° and 175°C Journal of The Electrochemical Society. ,vol. 120, pp. 459- 465 ,(1973) , 10.1149/1.2403477
G. Bianchi, P. Longhi, Copper in sea-water, potential-pH diagrams Corrosion Science. ,vol. 13, pp. 853- 864 ,(1973) , 10.1016/S0010-938X(73)80067-8
Jozsef Venczel, Gösta Wranglén, Elektrochemische untersuchungen von weichem kohlenstoffstahl unter mechanischer belastung in ätzalkali- und nitratlösungen Corrosion Science. ,vol. 4, pp. 137- 158 ,(1964) , 10.1016/0010-938X(64)90015-0
R.K. Flatt, P.A. Brook, The effects of anion concentration on anodic polarization of copper, zinc, and bra's Corrosion Science. ,vol. 11, pp. 185- IN3 ,(1971) , 10.1016/S0010-938X(71)80134-8
J. Venzcel, L. Knutsson, G. Wranglen, Korrosionsgeschwindigkeit und stoffkrauspoch in strömender NaCl-Lösung Corrosion Science. ,vol. 4, pp. 1- 13 ,(1964) , 10.1016/0010-938X(64)90003-4
M. Turner, P.A. Brook, The anodic behaviour of copper in static and flowing hydrochloric acid solutions Corrosion Science. ,vol. 13, pp. 973- 983 ,(1973) , 10.1016/S0010-938X(73)80080-0
C.H. Bonfiglio, H.C. Albaya, O.A. Cobo, The kinetics of the anodic dissolution of copper in acid chloride solutions Corrosion Science. ,vol. 13, pp. 717- 724 ,(1973) , 10.1016/S0010-938X(73)80010-1