Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica
作者： Jun Li , Yanmei Zhang , Difei Han , Qiang Gao , Can Li
DOI: 10.1016/J.MOLCATA.2008.09.027
关键词:
摘要: Ru-tsdpen (tsdpen=n-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) derived catalyst was firstly immobilized in the magnetic siliceous mesocellular foam material. this heterogeneous afforded high catalytic activities and ee values asymmetric transfer hydrogenation of imine hcooh-et(3)n system aromatic ketones aqueous hcoona. furthermore, showed an excellent durability can be reused conveniently by external magnet for at least nine times without noticeable loss values. (c) 2008 published elsevier b.v.
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sci-hub.se 参考文章(34)
Dong Kee Yi, Su Seong Lee, Georgia C. Papaefthymiou, Jackie Y. Ying, Nanoparticle Architectures Templated by SiO2/Fe2O3 Nanocomposites Chemistry of Materials. ,vol. 18, pp. 614- 619 ,(2006) , 10.1021/CM0512979
Choong Eui Song, Sang-gi Lee, Supported chiral catalysts on inorganic materials Chemical Reviews. ,vol. 102, pp. 3495- 3524 ,(2002) , 10.1021/CR0103625
Nobuyuki Uematsu, Akio Fujii, Shohei Hashiguchi, Takao Ikariya, Ryoji Noyori, Asymmetric Transfer Hydrogenation of Imines Journal of the American Chemical Society. ,vol. 118, pp. 4916- 4917 ,(1996) , 10.1021/JA960364K
A. B. Bourlinos, A. Simopoulos, N. Boukos, D. Petridis, Magnetic Modification of the External Surfaces in the MCM-41 Porous Silica: Synthesis, Characterization, and Functionalization Journal of Physical Chemistry B. ,vol. 105, pp. 7432- 7437 ,(2001) , 10.1021/JP010286+
Raed Abu-Reziq, Howard Alper, Dashan Wang, Michael L. Post, Metal Supported on Dendronized Magnetic Nanoparticles: Highly Selective Hydroformylation Catalysts Journal of the American Chemical Society. ,vol. 128, pp. 5279- 5282 ,(2006) , 10.1021/JA060140U
Akio Fujii, Shohei Hashiguchi, Nobuyuki Uematsu, Takao Ikariya, Ryoji Noyori, Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using a Formic Acid−Triethylamine Mixture Journal of the American Chemical Society. ,vol. 118, pp. 2521- 2522 ,(1996) , 10.1021/JA954126L
Liane M. Rossi, Fernanda P. Silva, Lucas L. R. Vono, Pedro K. Kiyohara, Evandro L. Duarte, Rosangela Itri, Richard Landers, Giovanna Machado, Superparamagnetic nanoparticle-supported palladium: a highly stable magnetically recoverable and reusable catalyst for hydrogenation reactions Green Chemistry. ,vol. 9, pp. 379- 385 ,(2007) , 10.1039/B612980C
Xiaofeng Wu, Jianke Liu, Devis Di Tommaso, Jonathan A. Iggo, C. Richard A. Catlow, John Bacsa, Jianliang Xiao, A Multilateral Mechanistic Study into Asymmetric Transfer Hydrogenation in Water Chemistry: A European Journal. ,vol. 14, pp. 7699- 7715 ,(2008) , 10.1002/CHEM.200800559
Shohei Hashiguchi, Akio Fujii, Jun Takehara, Takao Ikariya, Ryoji Noyori, Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes Journal of the American Chemical Society. ,vol. 117, pp. 7562- 7563 ,(1995) , 10.1021/JA00133A037
Daniel J Bayston, Catherine B Travers, Mario E.C Polywka, Synthesis and evaluation of a chiral heterogeneous transfer hydrogenation catalyst Tetrahedron-asymmetry. ,vol. 9, pp. 2015- 2018 ,(1998) , 10.1016/S0957-4166(98)00214-6