Syntheses and characterization of dinuclear cadmium(II) diimine complexes with bridging functionalized thiolate ligands

作者: K.S. Anjali , Yung-Lin Pui , Vivian Wing-Wah Yam , Jagadese J. Vittal

DOI: 10.1016/S0020-1693(01)00438-8

关键词:

摘要: Abstract A series of cationic dinuclear cadmium (II) diimine complexes with bridging functionalized thiolates have been prepared and characterized. The crystal structures [(bpy) 4 Cd 2 (μ-SC 6 H 5 ) ](ClO ( 1 NH -4) determined. photophysical electrochemical properties these also reported.

参考文章(18)
Eric Block, Christopher M. Rayner, Advances in Sulfur Chemistry ,(1992)
Jagadese J. Vittal, Philip A. W. Dean, Nicholas C. Payne, Metal-selenolate chemistry: stereochemistry of adamantane-type clusters of formula [(μ-SePh)6(MSePh)4]2− (M = Zn and Cd) Canadian Journal of Chemistry. ,vol. 70, pp. 792- 801 ,(1992) , 10.1139/V92-104
Richard H. Holm, Pierre Kennepohl, Edward I. Solomon, Structural and Functional Aspects of Metal Sites in Biology Chemical Reviews. ,vol. 96, pp. 2239- 2314 ,(1996) , 10.1021/CR9500390
P.J. Blower, J.R. Dilworth, Thiolato-complexes of the transition metals Coordination Chemistry Reviews. ,vol. 76, pp. 121- 185 ,(1987) , 10.1016/0010-8545(87)85003-8
Ian G. Dance, The structural chemistry of metal thiolate complexes Polyhedron. ,vol. 5, pp. 1037- 1104 ,(1986) , 10.1016/S0277-5387(00)84307-7
Jesus A. Castro, Jaime Romero, Jose A. García-Vazquez, Antonio Sousa, Jon Zubieta, Yuanda Chang, Electrochemical synthesis and crystal structure of bis(4-methyl-6-trifluoromethylpyrimidine-2-thionate) cadmium(II) Polyhedron. ,vol. 15, pp. 2741- 2745 ,(1996) , 10.1016/0277-5387(95)00550-1
Rosa Castro, Jose A. Garcia-Vazquez, Jaime Romero, Antonio Sousa, Charles A. McAuliffe, Robin Pritchard, Electrochemical synthesis of benzothiazole-2-thionato complexes of nickel(II), Zinc(II) and cadmium(II): the crystal structure of 2,2′-bipyridine bis(benzothiazole-2-thionato)zinc(II) Polyhedron. ,vol. 12, pp. 2241- 2247 ,(1993) , 10.1016/S0277-5387(00)88263-7