Enhanced tunability of sandwich-like structural barium strontium titanate thin films on stainless steel substrates

作者: Hanting Dong , Guoping Lu , Dengren Jin , Jianguo Chen , Jinrong Cheng

DOI: 10.1007/S10853-016-0093-3

关键词:

摘要: Barium strontium titanate (BST) thin films deposited on stainless steel (SS) substrates can be expected for their potential applications in MEMS-structure tunable microwave devices. In this paper, two sandwich-like structures with varied average Ba/Sr ratio of BST films, Ba0.6Sr0.4TiO3 layer the middle or at ends, LaNiO3 buffered SS were fabricated by sol–gel technique, and meanwhile theoretically carried out via a modified phenomenological model. Results show that dielectric constant tunability such tailored structures. When is unchanged, structure smaller lattice parameter than top/bottom achieve larger resulting from its compressive misfit strain, which has been qualitatively characterized X-ray diffraction Raman spectra. Especially, largest reaches 30 % under electric field 300 kV cm−1 locating Ba0.4Sr0.6TiO3 layers ends. Furthermore, experimental constants tunabilities are good agreement calculated data, instructing properties unchanged changing to adjust strain each uniform layer. This implies multilayer also designed theory.

参考文章(26)
L. J. Sinnamon, R. M. Bowman, J. M. Gregg, Investigation of dead-layer thickness in SrRuO3/Ba0.5Sr0.5TiO3/Au thin-film capacitors Applied Physics Letters. ,vol. 78, pp. 1724- 1726 ,(2001) , 10.1063/1.1356731
Radhapiyari Laishram, S.K. Pandey, O.P. Thakur, D.K. Bhattacharya, Dielectric and optical properties of Ba0.6Sr0.4Ti0.99Fe0.01O3 thin films deposited by pulsed laser deposition technique for microwave tunable devices Journal of Alloys and Compounds. ,vol. 579, pp. 205- 208 ,(2013) , 10.1016/J.JALLCOM.2013.06.057
Z.-G. Ban, S. P. Alpay, Phase diagrams and dielectric response of epitaxial barium strontium titanate films: A theoretical analysis Journal of Applied Physics. ,vol. 91, pp. 9288- 9296 ,(2002) , 10.1063/1.1473675
A. Rouahi, A. Kahouli, A. Sylvestre, E. Defaÿ, B. Yangui, Impedance spectroscopic and dielectric analysis of Ba0.7Sr0.3TiO3 thin films Journal of Alloys and Compounds. ,vol. 529, pp. 84- 88 ,(2012) , 10.1016/J.JALLCOM.2012.02.137
C. V. Weiss, M. B. Okatan, S. P. Alpay, M. W. Cole, E. Ngo, R. C. Toonen, Compositionally graded ferroelectric multilayers for frequency agile tunable devices Journal of Materials Science. ,vol. 44, pp. 5364- 5374 ,(2009) , 10.1007/S10853-009-3514-8
N. A. Pertsev, A. G. Zembilgotov, A. K. Tagantsev, Effect of Mechanical Boundary Conditions on Phase Diagrams of Epitaxial Ferroelectric Thin Films Physical Review Letters. ,vol. 80, pp. 1988- 1991 ,(1998) , 10.1103/PHYSREVLETT.80.1988
F. Stemme, M. Bruns, H. Geßwein, M. Schroeder, M. Sazegar, M. D. Drahus, R.-A. Eichel, F. Paul, C. Azucena, J. R. Binder, Fabrication and characterization of iron and fluorine co-doped BST thin films for microwave applications Journal of Materials Science. ,vol. 48, pp. 3586- 3596 ,(2013) , 10.1007/S10853-013-7156-5
Xiaohua Sun, Ying Yang, Qiaoling Zhang, Xin Zhou, Zongzhi Hu, Caihua Huang, Enhanced dielectric and tunable properties of barium strontium titanate thin films through introducing Nd(Zn1/2Ti1/2)O3 and adjusting Ba/Sr Journal of Materials Science. ,vol. 49, pp. 1058- 1065 ,(2014) , 10.1007/S10853-013-7783-X
Jingji Zhang, Jiwei Zhai, Xiujian Chou, Jun Shao, Xiang Lu, Xi Yao, Microwave and infrared dielectric response of tunable Ba1−xSrxTiO3 ceramics Acta Materialia. ,vol. 57, pp. 4491- 4499 ,(2009) , 10.1016/J.ACTAMAT.2009.06.011