AGET ATRP of methyl methacrylate catalyzed by FeCl3/iminodiacetic acid in the presence of air
作者： Lifen Zhang , Zhenping Cheng , Suping Shi , Qinghua Li , Xiulin Zhu
DOI: 10.1016/J.POLYMER.2008.04.057
关键词:
摘要: The recently developed living free-radical polymerization system, atom transfer radical polymerization using activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP), was used for methyl methacrylate (MMA) polymerization in the presence of a limited amount of air, using a novel catalyst system based on iron (FeCl3) complexes with iminodiacetic acid (IDA) and using ascorbic acid (VC) as a reducing agent. The kinetics of AGET ATRPs of MMA with different amounts of VC in the presence of air was …
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