The vibrational Zeeman effect in HC ≡ CF and DC ≡ CF
作者： W. Hüttner , H.K. Bodenseh , P. Nowicki
DOI: 10.1080/00268977800100551
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摘要: The magnetic-field splittings of the J=1→2 l-type doublets HCCF and DCCF, in their two bending modes, have been analysed to obtain information on vibrationally induced moments. vibrational g factors isotopic species are ‖ H v =0·4307(14) D =0·2193(13), v=(00011 0), as well =0·0472(20) =0·0462(19), v=(000011). signs determined relative that ground-state factor, ⊥ 0, which turn is obtained from effect. values ξ⊥ -ξ‖ similar those ground state. nuclear contributions were calculated via normal coordinates, a substantial electronic contribution was found.
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