Facile syntheses of the metallacyclic rings Pt–C–P–C, Pt–N–P–N and Pt–N–S–N; crystal structures of [Pt{CH(COPh)P(O)(Ph)CH(COPh)}(PPh3)2] and [Pt{C(CO2Me)C(CO2Me)NHS(O)2NH}(PMePh2)2]
作者： Raymond D. W. Kemmitt , Simon Mason , Mark R. Moore , John Fawcett , David R. Russell
DOI: 10.1039/C39900001535
关键词:
摘要: Reaction of PhCOCH2P(O)(Ph)CH2COPh, RNHP(O)(Ph)NHR or RNHS(O)2NHR (R = H Ph) with cis-[PtCl2L2](L PPh3 PMePh2; L2= Ph2PCH2CH2PPh2 cycloocta-1,5-diene) in the presence silver(I) oxide gives metallacyclic complexes type [[graphic omitted]H(COPh)}L2], omitted]R} L2] omitted]R}L2] respectively; single crystal X-ray studies on omitted]H(COPh)}(PPh3)2] and insertion product omitted]H}(PMePh2)2] establish puckered metallacycles, oxygen platinaphosphetane-3-oxide adopting an equatorial environment.
rsc.org
sci-hub.se 参考文章(15)
M.D. Jones, R.D.W. Kemmitt, Trimethylenemethane metal complexes Advances in Organometallic Chemistry. ,vol. 27, pp. 279- 309 ,(1987) , 10.1016/S0065-3055(08)60029-5
Ivan P. Parkin, Alexandra M. Z. Slawin, David J. Williams, J. Derek Woollins, Facile synthesis of SN and S–N–O complexes in liquid ammonia; X-ray structure of Pt[(HN)2SO2](PPh2Me)2 Journal of The Chemical Society, Chemical Communications. pp. 1060- 1061 ,(1989) , 10.1039/C39890001060
A. Fitzgerald, J. A. Campbell, G. D. Smith, C. N. Caughlan, S. E. Cremer, Solid-state studies on crowded molecules. Crystal and molecular structures of 2,2,3-trimethyl-1-phenylphosphetane 1-oxide and 2,2,3,3,4-pentamethyl-1-phenylphosphetane 1-oxide Journal of Organic Chemistry. ,vol. 43, pp. 3513- 3517 ,(1978) , 10.1021/JO00412A021
John. Fawcett, William. Henderson, Michael D. Jones, Raymond D. W. Kemmitt, David R. Russell, Brenda. Lam, Sung Kwon. Kang, Thomas A. Albright, Chemistry of metallacyclobutan-3-one (.eta.3-oxodimethylenemethane) complexes. 6. The synthesis, structure, and bonding in Pt[.eta.3-CH2C(O)CH2](PPh3)2.cntdot.CH2Cl2 Organometallics. ,vol. 8, pp. 1991- 1997 ,(1989) , 10.1021/OM00110A025
Ahmed Imran, Raymond D. W. Kemmitt, Andrew J. W. Markwick, Peter McKenna, David R. Russell, Lesley J. S. Sherry, Chemistry of metallacyclobutanones. Part 3. Reactions of heptane-2,4,6-trione and 1,5-diphenylpentane-1,3,5-trione with some carbonate complexes of platinum(II); X-ray crystal structures of [Pt{CH(COMe)COCH(COMe)}(PPh3)2] and [Pt{OC(CHCOPh)CHC(Ph)O}(PPh3)2] Journal of The Chemical Society-dalton Transactions. pp. 549- 554 ,(1985) , 10.1039/DT9850000549
Mazhar-ul-Haque, W. Horne, Structure of 2,2‐dimethyl‐1‐phenyl‐λ5‐phosphetane 1‐oxide Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 38, pp. 2944- 2946 ,(1982) , 10.1107/S0567740882010437
Barry M. Trost, Stephan Schneider, On an (oxatrimethylenemethane)palladium(0) complex. An unusual palladium(0)-catalyzed cyclopropanation Journal of the American Chemical Society. ,vol. 111, pp. 4430- 4433 ,(1989) , 10.1021/JA00194A043
William Henderson, Raymond D. W. Kemmitt, John Fawcett, Lesley J. S. Prouse, David R. Russell, The preparation and structures of metallathietane-3-oxides and –3,3-dioxides of platinum and palladium: the crystal structures of trans-2,4-dibenzoyl-1,1-bis(triphenylphosphine)platinathietane-3-oxide and trans-2,4-dibenzoyl-1,1-bis(triphenylphosphine)platinathietane-3,3-dioxide Journal of The Chemical Society, Chemical Communications. pp. 1791- 1793 ,(1986) , 10.1039/C39860001791
Ivan P. Parkin, J. Derek Woollins, Preparation and properties of [M{S2N3(SO2NH2)}(PR3)2] and [Pt{SO2(NH)2}(PR3)2] from reactions in liquid ammonia Journal of The Chemical Society-dalton Transactions. pp. 519- 523 ,(1990) , 10.1039/DT9900000519
Kwok W. Chiu, John Fawcett, William Henderson, Raymond D. W. Kemmitt, David R. Russell, Metallacyclic complexes. Synthesis of metallathietane-3,3-dioxide (metallacyclosulphone) complexes of platinum(II), palladium(II), and nickel(II); crystal structure of trans-2,4-diphenyl-1, 1-bis(triphenylarsine)platinathietane-3,3-dioxide Journal of The Chemical Society-dalton Transactions. pp. 733- 739 ,(1987) , 10.1039/DT9870000733