Europium gallium garnet (Eu3Ga5O12) and Eu3GaO6: Synthesis and material properties
作者： Kenji Sawada , Toshihiro Nakamura , Sadao Adachi
DOI: 10.1063/1.4964444
关键词:
摘要: Eu−Ga−O ternary compounds were synthesized from a mixture of cubic (c-) Eu2O3 and monoclinic Ga2O3 (β-Ga2O3) raw powders using the solid-state reaction method by calcination at Tc = 1200 °C. The structural optical properties investigated X-ray diffraction analysis, photoluminescence (PL) PL excitation (PLE) spectroscopy, Raman scattering measurements. Stoichiometric such as Eu3Ga5O12 (EGG) orthorhombic Eu3GaO6 molar ratios x = 0.375 0.75 [x≡Eu2O3/(Eu2O3 + Ga2O3)], respectively, together with end-point binary β-Ga2O3 (x = 0) (m-) (x = 1.0). change “cubic” to “monoclinic” in is due phase transition occurring Tc ≥ 1050 °C. In principle, perovskite-type EuGaO3 Eu4Ga2O9 can also be x = 0.5 0.667, respectively; however, stoichiometric could not this s...
scitation.org
harvard.edu
sci-hub.se 参考文章(38)
Ramón Cuscó, Núria Domènech-Amador, T Hatakeyama, T Yamaguchi, T Honda, Lluís Artús, Lattice dynamics of a mist-chemical vapor deposition-grown corundum-like Ga2O3 single crystal Journal of Applied Physics. ,vol. 117, pp. 185706- ,(2015) , 10.1063/1.4921060
Emilio Nogales, José A. García, Bianchi Méndez, Javier Piqueras, Red luminescence of Cr in β‐Ga2O3 nanowires Journal of Applied Physics. ,vol. 101, pp. 033517- ,(2007) , 10.1063/1.2434834
J. P. van der Ziel, L. G. Van Uitert, Antiresonance in the Optical Spectrum of Eu 3+ in Eu 3 Ga 5 O 12 :Pt Physical Review B. ,vol. 8, pp. 1835- 1845 ,(1973) , 10.1103/PHYSREVB.8.1835
Christiane Görller-Walrand, Koen Binnemans, Chapter 155 Rationalization of crystal-field parametrization Handbook on the Physics and Chemistry of Rare Earths. ,vol. 23, pp. 121- 283 ,(1996) , 10.1016/S0168-1273(96)23006-5
E. Nogales, B. Méndez, J. Piqueras, Cathodoluminescence from β‐Ga2O3 nanowires Applied Physics Letters. ,vol. 86, pp. 113112- ,(2005) , 10.1063/1.1883713
M. Toth, M. R. Phillips, Detection of Cr impurities in GaN by room temperature cathodoluminescence spectroscopy Applied Physics Letters. ,vol. 75, pp. 3983- 3985 ,(1999) , 10.1063/1.125528
Yoshinori Tokida, Sadao Adachi, Photoluminescence spectroscopy and energy-level analysis of metal-organic-deposited Ga2O3:Cr3+ films Journal of Applied Physics. ,vol. 112, pp. 063522- ,(2012) , 10.1063/1.4754517
U. V. Valiev, J. B. Gruber, G. W. Burdick, V. O. Pelenovich, M. E. Malysheva, Magnetooptics of magnetic-dipole transitions in the rare-earth paramagnetic garnets Optics and Spectroscopy. ,vol. 112, pp. 857- 863 ,(2012) , 10.1134/S0030400X12060227
T. Onuma, S. Fujioka, T. Yamaguchi, Y. Itoh, M. Higashiwaki, K. Sasaki, T. Masui, T. Honda, Polarized Raman spectra in β-Ga2O3 single crystals Journal of Crystal Growth. ,vol. 401, pp. 330- 333 ,(2014) , 10.1016/J.JCRYSGRO.2013.12.061
A Senyshyn, H Ehrenberg, L Vasylechko, J D Gale, U Bismayer, Computational study of LnGaO3 (Ln = La-Gd) perovskites Journal of Physics: Condensed Matter. ,vol. 17, pp. 6217- 6234 ,(2005) , 10.1088/0953-8984/17/39/008