摘要: Optisch aktive siliciumorganische Verbindungen mit funktionellen Gruppen am asymmetrischen Silicium wurden dargestellt. Ihre Untersuchung ergab, das viele Reaktionen siliciumorganischer stereospezifisch verlaufen. In dieser Arbeit wird die Konfigurationszuordnung fur sechs Schlusselverbindungen, welche α-Naphthyl-phenylmethyl-silyl-Gruppe enthalten, Hilfe chemischer und physikalischer Methoden beschrieben. Ferner werden Stereochemie einer Reihe von stereospezifischen dargelegt grundlegenden Beziehungen zwischen der den Reaktionsmechanismen monofunktioneller vom Typ R3SiY diskutiert.
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