The Structure and Reactivity of Organo-Phosphorus Compounds

摘要: Publisher Summary Structural and mechanistic investigations of organo-phosphorus compounds have received considerable stimulus in recent years because the importance nucleic acids, coenzymes, allylic pyrophosphates living systems. Thus, an organic phosphorus chemistry analogous to carbon has rapidly developed. The reactions such are usually classified under since same experimental techniques used, some common both elements. From electronic point view, however, at a atom should undoubtedly be as inorganic, relationship between structure reactivity organophosphorus is therefore interest theoretical studies inorganic chemistry. In present review we shall concerned primarily with structural description 4- 5-coordinated attempt provide general basis for interpretation their reactivity.