Photoionization of argon clusters in the Ar 3s → np Rydberg resonance region

作者: H Zhang , D Rolles , J D Bozek , N Berrah

DOI: 10.1088/0953-4075/42/10/105103

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摘要: The photoionization of argon clusters with an average size 270 atoms per cluster was investigated in the vicinity Ar 3s → np autoionizing resonances using angle-resolved time-of-flight photoelectron spectroscopy. 3p outer-valence spectra were measured as two-dimensional maps that show resonance profiles for free well cluster. For first time, partial yields and angular distributions two spin–orbit components are reported a function photon energy. photoelectrons differ substantially from atomic ones and, moreover, allow identification bulk surface resonances.

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