Crystal structure of radical cation salt (BEDT-TTF)4(GaCl4)2 · C6H5CH3
作者： L. V. Zorina , S. S. Khasanov , B. Zh. Narymbetov , R. P. Shibaeva , A. I. Kotov
DOI: 10.1134/1.1358397
关键词:
摘要: A new radical cation salt based on bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with the tetrahedral anion GaCl 4 − , namely, (BEDT-TTF)4(GaCl4)2 · C6H5CH3, has been synthesized. The crystal structure of this is determined by X-ray diffraction analysis [a = 31.757(2) A, b 6.8063(3) c 34.879(2) β 90.453(4)°, V 7538.8(7) A3, space group I2/c, and Z 4]. In structure, layers alternate along c-axis. consist tetrahedra solvent molecules. packing BEDT-TTF molecules in layer differs from that known (BEDT-TTF)2GaCl4, even though both compounds exhibit semiconductor properties.
springer.com
harvard.edu
sci-hub.se 参考文章(16)
David B. Amabilino, Jaume Veciana, Concepció Rovira, Supramolecular engineering of synthetic metallic materials : conductors and magnets Kluwer Academic Publishers. ,(1999)
Jack M. Williams, Hau H. Wang, Thomas J. Emge, Urs Geiser, Mark A. Beno, Peter C. W. Leung, K. Douglas Carlson, Robert J. Thorn, Arthur J. Schultz, Myung-Hwan Whangbo, Rational Design of Synthetic Metal Superconductors Progress in Inorganic Chemistry. ,vol. 35, pp. 51- 218 ,(2007) , 10.1002/9780470166369.CH2
Meiyu Luo, Takayuki Ishida, Akiko Kobayashi, Takashi Nogami, Electrical conductivities and crystal and band-electronic structures of a new phase of BEDT—TTF—bromide salt, (BEDT—TTF)2Br(H2O)3 Synthetic Metals. ,vol. 96, pp. 97- 102 ,(1998) , 10.1016/S0379-6779(98)00066-6
X. Bu, I. Cisarova, P. Coppens, B. Lederle, M. J. Naughton, Structure and conductivity of a new phase of 3,4;3',4'‐bis(ethylenedithio)‐2,2',5,5'‐tetrathiafulvalene hexafluorophosphate: γ‐(BEDT‐TTF)2PF6 Acta Crystallographica Section C-crystal Structure Communications. ,vol. 48, pp. 516- 519 ,(1992) , 10.1107/S0108270191009320
M. Kurmoo, M. Allan, R.H. Friend, D. Chasseau, G. Bravic, P. Day, (BEDT-TTF)2GaCl4: Structure, electrical and magnetic properties Synthetic Metals. ,vol. 42, pp. 2127- 2130 ,(1991) , 10.1016/0379-6779(91)92032-D
G. Bravic, D. Chasseau, J. Gaultier, M.J. Rosseinsky, M. Kurmoo, P. Day, A. Filhol, Structural properties of two modifications of hydrated BEDT-TTF chloride salts Synthetic Metals. ,vol. 42, pp. 2035- 2038 ,(1991) , 10.1016/0379-6779(91)92008-6
L. K. Montgomery, T. Burgin, C. Husting, L. Itlley, J. C. Huffman, K. D. Carlson, J. D. Dudek, G. A. Yaconi, U. Geiser, J. M. Williams, Synthesis and Characterization of Radical Cation Salts Derived from Tetraselenafulvalene and Bis(Ethy1enedithio)tetraselenafulvalene Molecular Crystals and Liquid Crystals. ,vol. 211, pp. 283- 288 ,(1992) , 10.1080/10587259208025827
M Kurmoo, D.R Talham, K.L Pritchard, P Day, A.M Stringer, J.A.K Howard, Structures of three new Ag(CN)2 salts of BEDT-TTF Synthetic Metals. ,vol. 27, ,(1988) , 10.1016/0379-6779(88)90398-0
Hatsumi Mori, Izumi Hirabayashi, Shoji Tanaka, Takehiko Mori, Hiroo Inokuchi, A new ambient-pressure organic superonductor, κ-(BEDT-TTF)2Ag(CN)2H2O (TC=5.0 K) Solid State Communications. ,vol. 76, pp. 35- 37 ,(1990) , 10.1016/0038-1098(90)90293-K
Urs Geiser, Hau H. Wang, Stephanie Kleinjan, Jack M. Williams, The Crystal and Molecular Structure of (BEDT-TTF)4(Hg2Br6)(1,1,2-Trichloroethane) Molecular Crystals and Liquid Crystals. ,vol. 181, pp. 125- 133 ,(1990) , 10.1080/00268949008035998