作者: Hiroki Adachi , Hiroaki Imoto , Seiji Watase , Kimihiro Matsukawa , Kensuke Naka
DOI: 10.1039/C5DT01490E
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摘要: As-stereogenic C2-symmetric 2,5-diaryl-cis-1,4-dihydro-1,4-diarsinines (2,5-diaryl-cis-DHDAs) were synthesized without volatile precursors. A racemic mixture of the ligands enantioselectively self-assembled into a dinuclear triple-stranded helicate with copper iodide in quantitative yield. In helicate, two metals bridged via three enantiomerically pure ligands.