Synthesis and coordination behaviors of P-stereogenic polymers
作者： Hiroaki Imoto , Yasuhiro Morisaki , Yoshiki Chujo
DOI: 10.1039/C0CC03120H
关键词:
摘要: Optically active polymers containing P-stereogenic bisphosphine and 1,2,3-triazole units in the main chain were obtained by copper-catalyzed Huisgen cycloaddition. The repeating unit of polymer adopted bidentate as well tetradentate coordination, leading to change conformations via complexation with transition metals.
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