Influence of gaseous atmosphere on corona-induced degradation of aqueous phenol

作者: D Hayashi , W F L M Hoeben , G Dooms , E M van Veldhuizen , W R Rutgers

DOI: 10.1088/0022-3727/33/21/315

关键词:

摘要: The phenol degradation processes by pulsed corona discharges are investigated under three kinds of discharge atmosphere (air, argon and oxygen). temporal variations the concentrations intermediate products monitored LIF spectroscopy. species identified spectral analysis. It is clarified that oxidative gaseous reagents produced from O2 those H2O degrade to with comparable rates. via gives rise formation molecules exhibiting fluorescence at 400-500 nm, in addition dihydroxybenzene (DHB), while produces only DHB. play an important role conversion

参考文章(15)
C. Hibert, I. Gaurand, O. Motret, J. M. Pouvesle, [OH(X)] measurements by resonant absorption spectroscopy in a pulsed dielectric barrier discharge Journal of Applied Physics. ,vol. 85, pp. 7070- 7075 ,(1999) , 10.1063/1.370514
H.D. Bist, J.C.D. Brand, D.R. Williams, The 2750-Å band system of phenol Journal of Molecular Spectroscopy. ,vol. 24, pp. 413- 467 ,(1967) , 10.1016/0022-2852(67)90105-1
H.D. Bist, J.C.D. Brand, D.R. Williams, The 2750-Å electronic band system of phenol: Part I. The in-plane vibrational spectrum Journal of Molecular Spectroscopy. ,vol. 21, pp. 76- 98 ,(1966) , 10.1016/0022-2852(66)90123-8
David R. Hanson, James B. Burkholder, Carleton J. Howard, A. R. Ravishankara, Measurement of hydroxyl and hydroperoxy radical uptake coefficients on water and sulfuric acid surfaces The Journal of Physical Chemistry. ,vol. 96, pp. 4979- 4985 ,(1992) , 10.1021/J100191A046
P Sunka, V Babický, M Clupek, P Lukes, M Simek, J Schmidt, M Cernák, Generation of chemically active species by electrical discharges in water Plasma Sources Science and Technology. ,vol. 8, pp. 258- 265 ,(1999) , 10.1088/0963-0252/8/2/006
Giel Berden, W. Leo Meerts, Michael Schmitt, Karl Kleinermanns, HIGH RESOLUTION UV SPECTROSCOPY OF PHENOL AND THE HYDROGEN BONDED PHENOL/WATER CLUSTER Journal of Chemical Physics. ,vol. 104, pp. 972- 982 ,(1996) , 10.1063/1.470821
Bing Sun, Masayuki Sato, J. S. Clements, Oxidative Processes Occurring When Pulsed High Voltage Discharges Degrade Phenol in Aqueous Solution Environmental Science & Technology. ,vol. 34, pp. 509- 513 ,(2000) , 10.1021/ES990024+
Bing Sun, Masayuki Sato, J S Clements, Use of a pulsed high-voltage discharge for removal of organic compounds in aqueous solution Journal of Physics D. ,vol. 32, pp. 1908- 1915 ,(1999) , 10.1088/0022-3727/32/15/319
A.A. Joshi, B.R. Locke, P. Arce, W.C. Finney, Formation of hydroxyl radicals, hydrogen peroxide and aqueous electrons by pulsed streamer corona discharge in aqueous solution Journal of Hazardous Materials. ,vol. 41, pp. 3- 30 ,(1995) , 10.1016/0304-3894(94)00099-3
O. C. Bridgeman, E. W. Aldrich, Vapor Pressure Tables for Water Journal of Heat Transfer. ,vol. 86, pp. 279- 286 ,(1964) , 10.1115/1.3687121