Intramolecular electron transfer

摘要: In most of the oxidation-reduction reactions involving net electron transfer which have been studied, experimental results yield only second order rates, and thus reflect barrier to bringing reactants together as well that for act itself. Recent advances in synthetic procedures make it possible measure an intramolecular or first process, complexes containing Co(III) Ru(II) oxidizing reducing agents respectively a wide variety bridging groups. Systems groups mediate transfer, others, serve define separation agent centres become accessible study. somewhat related class reactions, particular ligand complex is converted by external means agent, rate reduction metal ion damaged measured, process. Closely principle work referred are studies on mixed valence such as Figure options Download full-size image Download PowerPoint slide where between ruthenium (II) (III) end can be considered. But two classes differ dramatically because latter system there no chemistry associated with sense bonds broken formed transfer. The fact require different approaches their study feature elements interest from those exhibited Co(III)-Ru(II) class. principles underlying behaviour molecules will outlined, obtained properties described.