Well-defined phosphonated homo- and copolymers via direct ring opening metathesis polymerization
作者： Bahar Bingöl , Anja Kroeger , Patric Jannasch
DOI: 10.1016/J.POLYMER.2013.10.018
关键词:
摘要: Phosphonated polymers with a well-defined molecular weight, composition, and architecture have been prepared via ring opening metathesis polymerization (ROMP) of diethyl phosphonate norbornene imides at room temperature for the first time. ROMP gave broad range phosphonated homopolymers, statistical, diblock triblock copolymers based on poly(norbornene imide)s low polydispersity (1.09-1.32) Complete hydrolysis under mild conditions yielded phosphonic acid derivatives. Thermogravimetric analysis indicated high thermal thermo-oxidative stability polymers. Free standing transparent films good mechanical were obtained from functional copolymers. Combining these basic properties advantages mentioned above make promising pathway accessing wide diversity macromolecular structures. These new will open perspectives in advanced application areas such as medicine membrane science, which require level control over polymer structure.
archives-ouvertes.fr
mpg.de
elsevier.com
sci-hub.se 参考文章(36)
Julien Parvole, Patric Jannasch, Polysulfones grafted with poly(vinylphosphonic acid) for highly proton conducting fuel cell membranes in the hydrated and nominally dry state Macromolecules. ,vol. 41, pp. 3893- 3903 ,(2008) , 10.1021/MA800042M
Anke Zeller, Anna Musyanovych, Michael Kappl, Anitha Ethirajan, Martin Dass, Dilyana Markova, Markus Klapper, Katharina Landfester, Nanostructured coatings by adhesion of phosphonated polystyrene particles onto titanium surface for implant material applications. ACS Applied Materials & Interfaces. ,vol. 2, pp. 2421- 2428 ,(2010) , 10.1021/AM1004305
Martha Millaruelo, Volker Steinert, Hartmut Komber, Rainer Klopsch, Brigitte Voit, Synthesis of Vinylphosphonic Acid Anhydrides and their Copolymerization with Vinylphosphonic Acid Macromolecular Chemistry and Physics. ,vol. 209, pp. 366- 374 ,(2008) , 10.1002/MACP.200700377
Kurt Stubenrauch, Gerhard Fritz-Popovski, Elisabeth Ingolić, Werner Grogger, Otto Glatter, Franz Stelzer, Gregor Trimmel, Microphase Separation Study of Amphiphilic ROMP Block Copolymers by SAXS and TEM Macromolecules. ,vol. 40, pp. 4592- 4600 ,(2007) , 10.1021/MA070181Q
Stephan Salzinger, Bernhard Rieger, Rare Earth Metal-Mediated Group Transfer Polymerization of Vinylphosphonates Macromolecular Rapid Communications. ,vol. 33, pp. 1327- 1345 ,(2012) , 10.1002/MARC.201200278
Mark Ingratta, Matti Elomaa, Patric Jannasch, Grafting poly(phenylene oxide) with poly(vinylphosphonic acid) for fuel cell membranes Polymer Chemistry. ,vol. 1, pp. 739- 746 ,(2010) , 10.1039/B9PY00390H
Lucas Montero De Espinosa, Juan C. Ronda, Marina Galià, Virginia Cádiz, Michael A.R. Meier, Fatty acid derived phosphorus‐containing polyesters via acyclic diene metathesis polymerization Journal of Polymer Science Part A. ,vol. 47, pp. 5760- 5771 ,(2009) , 10.1002/POLA.23620
Masaaki Yamabe, Katsuyuki Akiyama, Yonezoh Akatsuka, Masao Kato, Novel phosphonated perfluorocarbon polymers European Polymer Journal. ,vol. 36, pp. 1035- 1041 ,(2000) , 10.1016/S0014-3057(99)00158-5
Bahar Bingöl, Gene Hart-Smith, Christopher Barner-Kowollik, Gerhard Wegner, Characterization of oligo(vinyl phosphonate)s by high-resolution electrospray ionization mass spectrometry: Implications for the mechanism of polymerization Macromolecules. ,vol. 41, pp. 1634- 1639 ,(2008) , 10.1021/MA702225K
Christopher W. Bielawski, Robert H. Grubbs, Living ring-opening metathesis polymerization Progress in Polymer Science. ,vol. 32, pp. 1- 29 ,(2007) , 10.1016/J.PROGPOLYMSCI.2006.08.006