Fatty acid derived phosphorus‐containing polyesters via acyclic diene metathesis polymerization
作者： Lucas Montero De Espinosa , Juan C. Ronda , Marina Galià , Virginia Cádiz , Michael A.R. Meier
DOI: 10.1002/POLA.23620
关键词: Ring-opening metathesis polymerisation 、 Organic chemistry 、 Polymerization 、 Comonomer 、 Polyester 、 Chemistry 、 Polymer chemistry 、 Copolymer 、 Metathesis 、 Polymer 、 Acyclic diene metathesis
摘要: The acyclic diene metathesis (ADMET) polymerization of a phosphoruscontaining α,ω-diene prepared from plant oil derived building block is reported. Different ruthenium based catalysts and conditions were tested to optimize the ADMET this monomer. Undecylenyl undecenoate was used as fully renewable comonomer obtain polyesters with different phosphorus contents increase content final polymers. Copolymerization caused marked variations in molecular weights leading 6 38 KDa. effect temperature thermal properties copolymers studied their degradation flame retardant evaluated.
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