Synthesis and structural characterization of a novel trinickel cluster: {[Ni(H 2 L)(EtOH)] 2 (OAc) 2 Ni} · 2EtOH
作者： Wen-kui Dong , Jin-gui Duan , Gai-lan Liu
DOI: 10.1007/S11243-007-0240-4
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摘要: A novel trinuclear NiII cluster, {[Ni(H2L)(EtOH)]2(OAc)2Ni} · 2EtOH [H4L:5,5′-Dihydroxy-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol], has been synthesized and structurally characterized. The X-ray crystal structure of the cluster reveals that two acetates coordinate to three nickel ions through Ni–O–C–O–Ni bridges four μ-phenoxo oxygen atoms from [Ni(H2L)] units also ions. Around are all octahedral geometries.
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