Synthesis, Characterization, and Crystal Structure of a New CuII Complex with Salen-Type Ligand
作者： Yin-Xia Sun , Xiong-Hou Gao
DOI: 10.1080/15533174.2011.591329
关键词:
摘要: A new dinuclear CuII complex, [Cu2(3-MeOSalamo-2)(H2O)3]·2pic·CH3COCH3·H2O, has been synthesized by the reaction of copper(II) picrate tetrahydrate with H2(3-MeOSalamo-n) (n = 2). X-ray crystallographic analysis reveals that complex is a structure when O-alkyl chain length relatively short (two CH2 groups), while tetranuclear obtained becomes longer (four groups). In μ-phenoxo bridging, picratol, and intermolecular hydrogen bonds play important roles in assembling ions ligands. Interestingly, not only helical chain, but an infinite metal–water supramolecular structure.
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