3D hierarchical flower of copper molybdate Cu3Mo2O9: Synthesis, nanostructure and lithium storage properties

作者: Lifeng Zhang , Wenjie He , Yi Liu , Min Ling , Peng Zheng

DOI: 10.1016/J.JALLCOM.2017.06.175

关键词:

摘要: Abstract 3D hierarchical flowers of Cu 3 Mo 2 O 9 (CM) assembled with two-dimensional nanosheets have been fabricated via the structure transformation (OH) (MoO 4 ) (CMOH) nano-cuboids. The tracing in growth process CMOH nanocuboids reveals that nanoparticles (NPs) are first formed followed by dispersing reaction system, and finally self-assemble to construct cuboid-like single-nanocrystal 250 ± 20 nm length 100 ± 20 nm thickness. Subsequently, calcination air can transform as-synthesized into CM flowers. It is identified controllable synthesis its calcinations critical forming such flowers, whose features deliver high lithium storage capacity, good cycling stability excellent rate capability as anode for ion battery.

参考文章(33)
Yaping Chen, Borui Liu, Wei Jiang, Qi Liu, Jingyuan Liu, Jun Wang, Hongsen Zhang, Xiaoyan Jing, Coaxial three-dimensional CoMoO 4 nanowire arrays with conductive coating on carbon cloth for high-performance lithium ion battery anode Journal of Power Sources. ,vol. 300, pp. 132- 138 ,(2015) , 10.1016/J.JPOWSOUR.2015.09.011
Juan Xia, Le Xin Song, Wei Liu, Yue Teng, Li Zhao, Qing Shan Wang, Mao Mao Ruan, Construction of Cu3Mo2O9 nanoplates with excellent lithium storage properties based on a pH-dependent dimensional change Dalton Transactions. ,vol. 44, pp. 13450- 13454 ,(2015) , 10.1039/C5DT01645B
M. Qamar, K. Alhooshani, M.I. Ahmed, A.-M. Azad, B. Merzougui, Amelioration in the visible-light-driven photocatalysis by faceted WO3 nanocuboids Catalysis Communications. ,vol. 70, pp. 21- 25 ,(2015) , 10.1016/J.CATCOM.2015.07.009
Yu Zhou, Zengjing Guo, Wei Hou, Qian Wang, Jun Wang, Polyoxometalate-based phase transfer catalysis for liquid–solid organic reactions: a review Catalysis Science & Technology. ,vol. 5, pp. 4324- 4335 ,(2015) , 10.1039/C5CY00674K
Lidong Li, Yi Peng, Yonghai Yue, Ye Hu, Xiu Liang, Penggang Yin, Lin Guo, Synthesis of concave gold nanocuboids with high-index facets and their enhanced catalytic activity Chemical Communications. ,vol. 51, pp. 11591- 11594 ,(2015) , 10.1039/C5CC02106E
Jiasheng Xu, Dongfeng Xue, Hydrothermal synthesis of lindgrenite with a hollow and prickly sphere-like architecture Journal of Solid State Chemistry. ,vol. 180, pp. 119- 126 ,(2007) , 10.1016/J.JSSC.2006.09.030
Yu Chen, Jong-Min Lee, Guang-Rui Xu, Jiao-Jiao Hui, Tan Huang, Platinum nanocuboids supported on reduced graphene oxide as efficient electrocatalyst for the hydrogen evolution reaction Journal of Power Sources. ,vol. 285, pp. 393- 399 ,(2015) , 10.1016/J.JPOWSOUR.2015.03.131
Jaya Pal, Mainak Ganguly, Chanchal Mondal, Yuichi Negishi, Tarasankar Pal, Precursor salt assisted syntheses of high-index faceted concave hexagon and nanorod-like polyoxometalates Nanoscale. ,vol. 7, pp. 708- 719 ,(2015) , 10.1039/C4NR06309K
Le Xin Song, Jing Yang, Lei Bai, Fang Yun Du, Jie Chen, Mang Wang, Molecule-ion interaction and its effect on electrostatic interaction in the system of copper chloride and β-cyclodextrin. Inorganic Chemistry. ,vol. 50, pp. 1682- 1688 ,(2011) , 10.1021/IC1021609
Katikaneani Pavani, Arunachalam Ramanan, Influence of 2-Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions European Journal of Inorganic Chemistry. ,vol. 2005, pp. 3080- 3087 ,(2005) , 10.1002/EJIC.200500092