Unusual formation of a hex-3-ene-1,5-diyne-3-yl ligand from a buta-1,3-diyne in the Cp*2TiCl2–Mg system
作者： Paul-Michael Pellny , Frank G. Kirchbauer , Vladimir V. Burlakov , Anke Spannenberg , Uwe Rosenthal
DOI: 10.1039/A906777I
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摘要: The reaction of [Cp*2TiCl2] with equimolar amounts magnesium in the presence Me3SiCC–CCSiMe3 yields first early transition metal η3-enyne complex [Cp*2Ti{η3-Me3SiC3C(CCSiMe3)SiMe3}] 1 which is suggested to be an intermediate catalysed oligomerization reactions alk-1-ynes.
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