Synthesis, Structures, and Luminescent Properties of d10 Group 12 Metal Complexes with Substituted 2,2′-Bipyridine Ligands
作者： Xiao-ming Liu , Xiao-yue Mu , Hong Xia , Ling Ye , Wei Gao
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摘要: Four d10 group 12 metal complexes, 6-(2-methoxyphenyl)-2,2′-bipyridinezinc dichloride (2a), -mercury (2b), 6-[2-(dimethylamino)phenyl]-2,2′-bipyridinezinc (2c), and (2d), were synthesized the structures determined by single-crystal X-ray crystallography. Complexes 2a 2b are four-coordinate adopt a distorted tetrahedral geometry, while complexes 2c 2d five-coordinate with trigonal bipyramidal geometry for center. Luminescent properties of 2a–2d in both solution solid state studied. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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