The applicability of TMDSC to polymeric systems: General theoretical description based on the full heat capacity formulation

摘要: Temperature-modulated differential scanning calorimetry (TMDSC) has recently been introduced as a promising calorimetric technique. However, the added value of TMDSC in practice is still not very obvious, particular with respect to crystallization and melting. An important reason that evaluation less transparent than case other dynamic techniques since response also based on temperature. Moreover, temperature program applied critical. In this paper an overview given different aspects using general theoretical description full heat capacity formulation. It demonstrated processes studied aid can simply be classified into three distinct regimes, depending time scale susceptibility process modulation.