Gas hydrates in aqueous-organic systems

作者: W.J. Scanlon , O. Fennema

DOI: 10.1016/0011-2240(71)90047-2

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摘要: Abstract Linear crystallization velocities of hydrates (aqueous clathrates) type I ethylene oxide and II tetrahydrofuran were determined in simple solutions polyacrylamide gels supercooled from 3.1 to 24 °C. At any given degree supercooling, all hydrate-forming crystallized much more slowly than pure water, the hydrate oxide. Ethylene formed at a velocity greater even when designed bind approximately equal numbers water molecules during formation. In instances, presence gel decreased

参考文章(27)
H. R. Müller, M. v. Stackelberg, Feste Gashydrate II. Struktur und Raumchemie Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 58, pp. 25- 39 ,(1954) , 10.1002/BBPC.19540580105
B. Meuthen, M. v. Stackelberg, Feste Gashydrate. VII. Hydrate wasserlöslicher Äther Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 62, pp. 130- 131 ,(1958) , 10.1002/BBPC.19580620206
The Velocity of Ice Crystallisation through Supercooled Gelatin Gels Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 108, pp. 307- 323 ,(1925) , 10.1098/RSPA.1925.0077
G. Tammann, A. Büchner, Die Unterkühlungsfähigkeit des Wassers und die lineare Kristallisationsgeschwindigkeit des Eises in wäßrigen Lösungen Zeitschrift für anorganische und allgemeine Chemie. ,vol. 222, pp. 371- 381 ,(1935) , 10.1002/ZAAC.19352220405
G. Tammann, A. Büchner, Die lineare Kristallisationsgeschwindigkeit des Eises aus gewöhnlichem und schwerem Wasser Zeitschrift für anorganische und allgemeine Chemie. ,vol. 222, pp. 12- 16 ,(1935) , 10.1002/ZAAC.19352220103
C. S. Lindenmeyer, Bruce Chalmers, Growth Rate of Ice Dendrites in Aqueous Solutions The Journal of Chemical Physics. ,vol. 45, pp. 2807- 2808 ,(1966) , 10.1063/1.1728030
C. S. Lindenmeyer, G. T. Orrok, K. A. Jackson, B. Chalmers, Rate of Growth of Ice Crystals in Supercooled Water The Journal of Chemical Physics. ,vol. 27, pp. 822- 822 ,(1957) , 10.1063/1.1743849
Thomas C. W. Mak, Richard K. McMullan, Polyhedral Clathrate Hydrates. X. Structure of the Double Hydrate of Tetrahydrofuran and Hydrogen Sulfide The Journal of Chemical Physics. ,vol. 42, pp. 2732- 2737 ,(1965) , 10.1063/1.1703229
W. C. Macklin, B. F. Ryan, Habits of ice grown in supercooled water and aqueous solutions Philosophical Magazine. ,vol. 14, pp. 847- 860 ,(1966) , 10.1080/14786436608211977
L. C. Yang, W. B. Good, Crystallization rate of supercooled water in cylindrical tubes Journal of Geophysical Research. ,vol. 71, pp. 2465- 2469 ,(1966) , 10.1029/JZ071I010P02465