Fabrication of Low-Fouling Ultrafiltration Membranes Using a Hydrophilic, Self-Doping Polyaniline Additive

作者: Brian T. McVerry , James A. T. Temple , Xinwei Huang , Kristofer L. Marsh , Eric M. V. Hoek

DOI: 10.1021/CM401288R

关键词:

摘要: A simple, scalable method for fabricating fouling-resistant ultrafiltration membranes is described. self-doped, sulfonated form of polyaniline was blended into polysulfone (PSf) (UF) to enhance hydrophilicity and fouling resistance. Polyaniline in its base with fuming sulfuric acid, yielding (SPANi) a degree sulfonation ∼0.5 confirmed by XPS. The SPANi polymer dedoped dissolved solution N-methylpyrollidone at varying concentrations. During phase inversion membranes, redoped precipitated within the PSf membrane films facile one-step process. Composite containing increasing amounts were compared pure determine changes performance, hydrophilicity, antifouling characteristics. composite exhibit fluxes similar those maintain rejection properties current UF mem...

参考文章(42)
Li-Ping Zhu, Li Xu, Bao-Ku Zhu, Yong-Xiang Feng, You-Yi Xu, Preparation and characterization of improved fouling-resistant PPESK ultrafiltration membranes with amphiphilic PPESK-graft-PEG copolymers as additives Journal of Membrane Science. ,vol. 294, pp. 196- 206 ,(2007) , 10.1016/J.MEMSCI.2007.02.038
Shi Qiu, Liguang Wu, Xuejie Pan, Lin Zhang, Huanlin Chen, Congjie Gao, Preparation and properties of functionalized carbon nanotube/PSF blend ultrafiltration membranes Journal of Membrane Science. ,vol. 342, pp. 165- 172 ,(2009) , 10.1016/J.MEMSCI.2009.06.041
Robert N. Wenzel, RESISTANCE OF SOLID SURFACES TO WETTING BY WATER Industrial & Engineering Chemistry. ,vol. 28, pp. 988- 994 ,(1936) , 10.1021/IE50320A024
J PARK, M ACAR, A AKTHAKUL, W KUHLMAN, A MAYES, Polysulfone-graft-poly(ethylene glycol) graft copolymers for surface modification of polysulfone membranes. Biomaterials. ,vol. 27, pp. 856- 865 ,(2006) , 10.1016/J.BIOMATERIALS.2005.07.010
Helin HUA, Na LI, Linlin WU, Hui ZHONG, Guangxia WU, Zonghuan YUAN, Xiangwei LIN, Lianyi TANG, Anti-fouling ultrafiltration membrane prepared from polysulfone-graft-methyl acrylate copolymers by UV-induced grafting method Journal of Environmental Sciences-china. ,vol. 20, pp. 565- 570 ,(2008) , 10.1016/S1001-0742(08)62095-1
Bozena Kaeselev, John Pieracci, Georges Belfort, Photoinduced grafting of ultrafiltration membranes: comparison of poly(ether sulfone) and poly(sulfone) Journal of Membrane Science. ,vol. 194, pp. 245- 261 ,(2001) , 10.1016/S0376-7388(01)00544-0
Jiang Yue, Zhao H. Wang, Keith R. Cromack, Arthur J. Epstein, Alan G. MacDiarmid, Effect of sulfonic acid group on polyaniline backbone Journal of the American Chemical Society. ,vol. 113, pp. 2665- 2671 ,(1991) , 10.1021/JA00007A046