Regioselectivity of styrene carbonylation in the presence of palladium(II) complexes
作者： A. L. Lapidus , O. L. Eliseev , N. V. Zvyagintsev , L. T. Kondrat’ev
DOI: 10.1134/S0036024411050207
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摘要: The influence of a catalyst on regioselectivity styrene carbonylation in ionic liquids catalyzed by palladium(II) complexes was studied. mechanism the migration insertion at palladium-hydrogen bond determining regioselectrivity whole reaction, which is treated as electrophilic addition to multiple styrene, A study structure intermediate formed this stage performed using B3LYP method density functional theory.
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