作者: Wei Wang
DOI: 10.1107/S1600536808019272
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摘要: The title complex, [Mn(C7H6N5)2(H2O)2], was obtained by the in situ hydrothermal reaction of MnCl2 with 2-(2-pyridyl)acetonitrile presence NaN3. MnII atom, which is located on an inversion centre, has a distorted octahedral coordination geometry formed two water molecules and chelating ligands. Intermolecular hydrogen bonds π–π interactions (3.452 A) stabilize crystal structure lead to formation three-dimensional network.