C61Cl2. Synthesis and characterization of dichlorocarbene adducts of C60
作者： Minoru Tsuda , Takayuki Ishida , Takashi Nogami , Sadamu Kurono , Mamoru Ohashi
DOI: 10.1016/S0040-4039(00)91828-8
关键词:
摘要: Dichlorocarbene generated by pyrolysis of sodium trichloroacetate was found to add C60 in a benzene-diglyme mixed solvent. The products C60CCl2)n (n=1-3) were isolated means gel permeation chromatography eluted with toluene and characterized FAB mass spectroscopy. structure Of C60(CCl2) determined 13C NMR addition occurred at the 6-ring/6-ring junction, giving cyclopropane structure.
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sci-hub.se 参考文章(12)
Vincent M. Rotello, Jack B. Howard, Tapesh Yadav, M.Morgan Conn, Elisabetta Viani, Laura M. Giovane, Arthur L. Lafleur, Isolation of fullerene products from flames: Structure and synthesis of the C60-cyclopentadiene adduct Tetrahedron Letters. ,vol. 34, pp. 1561- 1562 ,(1993) , 10.1016/0040-4039(93)85006-I
P.-M. ALLEMAND, K. C. KHEMANI, A. KOCH, F. WUDL, K. HOLCZER, S. DONOVAN, G. GRUNER, J. D. THOMPSON, Organic molecular soft ferromagnetism in a fullerene c60. Science. ,vol. 253, pp. 301- 302 ,(1991) , 10.1126/SCIENCE.253.5017.301
R. Bakhtiar, C. M. Holznagel, D. B. Jacobson, Generation and characterization of isomeric iron-silylene and iron-silene cationic complexes in the gas phase Journal of the American Chemical Society. ,vol. 115, pp. 345- 347 ,(1993) , 10.1021/JA00054A050
Takeshi Akasaka, Wataru Ando, Kaoru Kobayashi, Shigeru Nagase, Reaction of C60 with silylene, the first fullerene silirane derivative Journal of the American Chemical Society. ,vol. 115, pp. 1605- 1606 ,(1993) , 10.1021/JA00057A072
T. SuzuKI, Q. LI, K. C. KHEMANI, F. WUDL, O. ALMARSSON, Systematic Inflation of Buckminsterfillerene C60: Synthesis of Diphenyl Fulleroids C61 to C66 Science. ,vol. 254, pp. 1186- 1188 ,(1991) , 10.1126/SCIENCE.254.5035.1186
W. Krätschmer, Lowell D. Lamb, K. Fostiropoulos, Donald R. Huffman, Solid C60: a new form of carbon Nature. ,vol. 347, pp. 354- 358 ,(1990) , 10.1038/347354A0
Andrea Vasella, Peter Uhlmann, Christian A. A. Waldraff, François Diederich, Carlo Thilgen, Fullerene Sugars: Preparation of Enantiomerically Pure, Spiro‐Linked C‐Glycosides of C60 Angewandte Chemie. ,vol. 31, pp. 1388- 1390 ,(1992) , 10.1002/ANIE.199213881
T. Suzuki, Q. Li, K. C. Khemani, F. Wudl, Dihydrofulleroid H3C61: synthesis and properties of the parent fulleroid Journal of the American Chemical Society. ,vol. 114, pp. 7301- 7302 ,(1992) , 10.1021/JA00044A055
Steven H. Hoke, Jay Molstad, Dominique Dilettato, Mary Jennifer Jay, Dean Carlson, Bart Kahr, R. Graham Cooks, Reaction of fullerenes and benzyne Journal of Organic Chemistry. ,vol. 57, pp. 5069- 5071 ,(1992) , 10.1021/JO00045A012
Fred McLafferty, Editorial Accounts of Chemical Research. ,vol. 25, pp. 97- 97 ,(1992) , 10.1021/AR00014A600