Two-dimensional molecular space with regular molecular structure.
作者： Ken Yao , Xiaoqing You , Liyi Shi , Wen Wan , Futao Yu
DOI: 10.1021/LA702700S
关键词:
摘要: A novel two-dimensional molecular space (layered carboxylpropylamidephenylsilica, CPAPhS) with regular carboxyl groups was successfully synthesized through grafting in the structure of layered (aminophenyl)silica using butanedioic anhydride. The regularly arranged CPAPhS can react various organic molecules amino and hydroxyl formation reactive intermediate catalyzers, such as SOCl2. In this research, an example used to prove reaction properties CPAPhS. reacted SOCl2 form acyl chloridepropylamidephenylsilica (ACPAPhS) then n-butylamine n-butyl alcohol n-butylamidepropylamidephenylsilica (BAPAPhS) n-butylesterpropylamidephenylsilica (BEPAPhS) structures. Layered showed potential a starting material for series with...
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