Ionic conductivity of double sodium-scandium and cesium-zirconium molybdates
作者： N. I. Sorokin
DOI: 10.1134/S1063783409060079
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摘要: The electrical properties of the Na3Sc(MoO4)3 and Cs2Zr(MoO4)3 compounds are investigated using impedance spectroscopy (1–106 Hz) in temperature range 100–650°C. Double molybdates form a fine-crystalline powder obtained by solid-phase synthesis air at 450–600°C for 20–50 h. It is found that dependence ionic conductivity ceramic samples exhibits anomalies temperatures 605 ± 5°C 425 15°C due to phase transitions, which confirmed data thermal analysis. Above superionic reaches 0.084 S/cm (650°C) 0.002 (462°C) Cs2Zr(MoO4)3.
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J MORALES, L HERNAN, E WANG, M TSAI, J LEE, M GREENBLATT, Ionic motion in A2In2Mo5O16 [A=Na, K, (Na, Li)] phases Solid State Ionics. ,vol. 38, pp. 275- 281 ,(1990) , 10.1016/0167-2738(90)90433-R
Jekabs Grins, Mats Nygren, Compositional dependence of the ionic conductivity of Na2.2Zn0.9(MoO4)2 with Zn partially replaced by Sc or Cd Solid State Ionics. pp. 859- 862 ,(1983) , 10.1016/0167-2738(83)90102-9
J.B. Goodenough, H.Y-P. Hong, J.A. Kafalas, Fast Na+-ion transport in skeleton structures Materials Research Bulletin. ,vol. 11, pp. 203- 220 ,(1976) , 10.1016/0025-5408(76)90077-5