In situ preparation and characterization of biocompatible acrylate‐terminated polyurethane containing chemically modified multiwalled carbon nanotube

作者: M. Alishiri , A. Shojaei

DOI: 10.1002/PC.24423

关键词:

摘要: Biodegradable acrylate-terminated polyurethane/acrylate (APUA) filled with 2-hydroxyethyl methacrylate functionalized carbon nanotube (CNT-HEMA) was prepared by in situ free radical crosslinking. CNT-HEMA enhanced crystallinity of soft domain and caused more phase separation between hard domains APUA. Tensile testing showed a considerable improvement elastic modulus (∼160%) tensile strength (∼30%) at 1 wt% loading. Morphological features APUA induced nanotubes were found to be dominant on mechanical properties APUA/CNT-HEMA. increased water contact angle APUA; however, wettability APUA/CNT-HEMA maintained acceptable range for biomedical applications. exhibited lower hydrophobic nature compared many CNT polyurethanes reported literature due HEMA functional group, making nanocomposites adequate POLYM. COMPOS., 2017. © 2017 Society Plastics Engineers

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