Stoichiometries and Equilibrium Constants of Cyclodextrin-Surfactant Complexations

作者: Noriaki Funasaki , Hiromi Yodo , Sakae Hada , Saburo Neya

DOI: 10.1246/BCSJ.65.1323

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摘要: General and rigorous theory for equilibrium concentrations of uncomplexed species 1 : 1, 2, 2 complexes cyclodextrin (D) surfactant has been developed applied to evaluate the binding constants these complexations from surface tension data aqueous solutions dodecyl maltoside (DM) with α-, β-, γ-D, reported by Saeger Muller-Fahrnow. The orders D DM are α-D > β-D γ-D. Those γ-D α-D. These explained on basis goodness fit chain into cavity. Furthermore, effects molar conductivity critical micelle concentration (cmc) an ionic is modified accounting change values sodium sulfate (SDS) ...

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