A novel synthetic method for 3-hydroxyhomoisoflavanone.

作者: Sang-sup Jew , Hyun-ah Kim , Hyeung-geun Park

DOI: 10.1007/BF02974001

关键词:

摘要: A novel synthetic method was developed for 3-hydroxyhomoisoflavanone. Treatment of aryllithium14 to aldehyde13 which obtained from dihydroxylation of10, followed by cycloetherification give 3-hydroxyhomoisoflavanones.

参考文章(11)
A. Leslie Gunatilaka, S. Sotheeswaran, S. Balasubramaniam, A. Indumathie Chandrasekara, H. Badra Sriyani, Studies on medicinal plants of Sri Lanka. III. Pharmacologically important alkaloids of some sida species. Planta Medica. ,vol. 39, pp. 66- 72 ,(1980) , 10.1055/S-2008-1074904
Robertson Pratt, Yoko Yuzuriha, Antibacterial Activitv of the Heartwood of Haematoxylon braziletto**University of California, School of Pharmacy, San Francisco 22 Journal of the American Pharmaceutical Association (Scientific ed.). ,vol. 48, pp. 69- 72 ,(1959) , 10.1002/JPS.3030480122
Franklin A. Davis, Bang-Chi Chen, A highly enantioselective synthesis of (R)- and (S)-5,7-odimethyleucomol Tetrahedron Letters. ,vol. 31, pp. 6823- 6826 ,(1990) , 10.1016/S0040-4039(00)97181-8
L. Farkas, A. Gottsegen, M. Nogradi, Synthesis of eucomin and (±)eucomol Tetrahedron Letters. ,vol. 9, pp. 4099- 4100 ,(1968) , 10.1016/S0040-4039(00)72872-3
Michio Namikoshi, Hiroyuki Nakata, Tamotsu Saitoh, Homoisoflavonoids from Caesalpinia sappan Phytochemistry. ,vol. 26, pp. 1831- 1833 ,(1987) , 10.1016/S0031-9422(00)82298-0
C. Moon, Y. Yun, J. Lee, H. Wagner, Y. Shin, Inhibition of lens-aldose reductase activity by brazilin and haematoxylin. Planta Medica. ,vol. 51, pp. 66- 67 ,(1985) , 10.1055/S-2007-969397
Anna Arnoldi, Angela Bassoli, Gigliola Borgonovo, Lucio Merlini, Synthesis and sweet taste of optically active (–)-haematoxylin and of some (±)-haematoxylin derivatives J. Chem. Soc., Perkin Trans. 1. pp. 2447- 2453 ,(1995) , 10.1039/P19950002447
Hiroshi Hikino, Takashi Taguchi, Hajime Fujimura, Yasuzo Hiramatsu, Antiinflammatory principles of Caesalpinia sappan wood and of Haematoxylon campechianum wood. Planta Medica. ,vol. 31, pp. 214- 220 ,(1977) , 10.1055/S-0028-1097516
Chang-Kiu Moon, Soo-Hwan Lee, Jin-Ho Chung, Seong-Gon Kim, Mung-Kiu Chung, Chang-Hyun Moon, Effects of brazilin on glucose metabolism in primary cultured rat hepatocytes Archives of Pharmacal Research. ,vol. 13, pp. 355- 358 ,(1990) , 10.1007/BF02858173
H. G. KRISHNAMURTY, B. PARKASH, T. R. SESHADRI, SYNTHESIS OF EUCOMIN, 4′-DEMETHYLEUCOMIN AND 5,7-DI-O-METHYLEUCOMOL ChemInform. ,vol. 5, ,(1974) , 10.1002/CHIN.197444243