Preferential solvation in mixed solvents.

作者: Yizhak Marcus

DOI: 10.1039/B205180J

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摘要: The Kirkwood–Buff integrals and the volume-corrected preferential solvation parameters for first shell of binary mixtures tetrahydrofuran with many organic solvents, calculated from reported thermodynamic data at temperatures which these were available, are reported. co-solvents include c-hexane, methyl-c-hexane, n-heptane, i-octane, benzene, toluene, ethylbenzene, 1-chlorobutane, dichloromethane, 1,2-dichloroethane, chloroform, 1,1,1-trichloroethane, tetrachlorom-ethane, tetrachloroethene, hexafluoro ethanol, 1-propanol, 2-propanol, dibutyl ether, acetic acid, acetone, dimethyl sulfoxide, tetramethylene sulfone (sulfolane), acetonitrile, pyrrolidine, triethylamine. discussed in terms interactions that occur.

参考文章(54)
Inés L. Acevedo, Graciela C. Pedrosa, Eleuterio L. Arancibia, Miguel Katz, Isothermal Vapor–Liquid Equilibria for the Ternary System 2-Propanol + Tetrahydrofuran + 1-Chlorobutane at 25°C Journal of Solution Chemistry. ,vol. 30, pp. 1029- 1037 ,(2001) , 10.1023/A:1013355411329
A. Valén, I. Gascón, C. Lafuente, J. S. Urieta, F. M. Royo, M. Postigo, Volumetric and Acoustic Properties of the Ternary Mixture 1-Butanol+1-Chlorobutane+Tetrahydrofuran at 283.15, 298.15, and 313.15 K International Journal of Thermophysics. ,vol. 23, pp. 1587- 1598 ,(2002) , 10.1023/A:1020892201382
Enrico Matteoli, Luciano Lepori, Solute–solute interactions in water. II. An analysis through the Kirkwood–Buff integrals for 14 organic solutes The Journal of Chemical Physics. ,vol. 80, pp. 2856- 2863 ,(1984) , 10.1063/1.447034
M. J. Blandamer, N. J. Hidden, K. W. Morcom, R. W. Smith, N. C. Treloar, M. J. Wootten, Thermodynamic, spectroscopic and ultrasonic absosrption studies of water + 1,3-dioxolane mixtures Transactions of the Faraday Society. ,vol. 65, pp. 2633- 2638 ,(1969) , 10.1039/TF9696502633
Yizhak Marcus, Preferential solvation in mixed solvents. Part 7.—Binary mixtures of water and alkanolamines J. Chem. Soc., Faraday Trans.. ,vol. 91, pp. 427- 430 ,(1995) , 10.1039/FT9959100427