Reduced graphene oxide supported titanium dioxide nanomaterials for the photocatalysis with long cycling life
作者： Yuan-Cheng Cao , Zhongtian Fu , Wenjun Wei , Linling Zou , Tie Mi
DOI: 10.1016/J.APSUSC.2015.08.036
关键词:
摘要: Abstract The reduced Graphene Oxide (rGO) supported TiO2 (rGO@TiO2) as the photocatalyst was synthesized and evaluated. oxided using chemical method AFM measurements showed that thickness of as-synthesized GO 3–5 nm which indicates 4–6 layers resultant graphene oxide. BET surface area 62.4 m2/g for 247.3 m2/g rGO@TiO2. Size distribution when rGO ratio increases from 5% to 15% (rGO/TiO2), rGO@TiO2 samples show better size in range 100 nm 200 nm. Photocatalysis test exposure time increased over 100 min, degradation rate could reach 96.4%. First order kinetics results much higher constant than TiO2. Reproducibility can keep rates at less 25 cycles. Results is a promising with long cycling life.
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Dong Liu, Wei Zi, Syed D Sajjad, Chiajen Hsu, Yi Shen, Mingsheng Wei, Fuqiang Liu, Reversible Electron Storage in an All-Vanadium Photoelectrochemical Storage Cell: Synergy between Vanadium Redox and Hybrid Photocatalyst ACS Catalysis. ,vol. 5, pp. 2632- 2639 ,(2015) , 10.1021/CS502024K
Chockalingam Karunakaran, Pazhamalai Vinayagamoorthy, Jayaraman Jayabharathi, Nonquenching of Charge Carriers by Fe3O4 Core in Fe3O4/ZnO Nanosheet Photocatalyst Langmuir. ,vol. 30, pp. 15031- 15039 ,(2014) , 10.1021/LA5039409
Jingsan Xu, Thomas J. K. Brenner, Zupeng Chen, Dieter Neher, Markus Antonietti, Menny Shalom, Upconversion-Agent Induced Improvement of g-C3N4 Photocatalyst under Visible Light ACS Applied Materials & Interfaces. ,vol. 6, pp. 16481- 16486 ,(2014) , 10.1021/AM5051263
Qiong-Qiong Ren, Xiao-Jun Yuan, Xiao-Rong Huang, Wei Wen, Yuan-Di Zhao, Wei Chen, In vivo monitoring of oxidative burst on aloe under salinity stress using hemoglobin and single-walled carbon nanotubes modified carbon fiber ultramicroelectrode. Biosensors and Bioelectronics. ,vol. 50, pp. 318- 324 ,(2013) , 10.1016/J.BIOS.2013.07.001
María D. Hernández-Alonso, Fernando Fresno, Silvia Suárez, Juan M. Coronado, Development of alternative photocatalysts to TiO2: Challenges and opportunities Energy and Environmental Science. ,vol. 2, pp. 1231- 1257 ,(2009) , 10.1039/B907933E
Yong Yu, Jun Chen, Zi-Ming Zhou, Yuan-Di Zhao, Facile synthesis of carbon nanotube-inorganic hybrid materials with improved photoactivity. Dalton Transactions. ,vol. 42, pp. 15280- 15284 ,(2013) , 10.1039/C3DT51673C
K. Srinivasu, Brindaban Modak, Swapan K. Ghosh, Porous Graphitic Carbon Nitride: A Possible Metal-free Photocatalyst for Water Splitting Journal of Physical Chemistry C. ,vol. 118, pp. 26479- 26484 ,(2014) , 10.1021/JP506538D
Yasumichi Matsumoto, Michio Koinuma, Shintaro Ida, Shinya Hayami, Takaaki Taniguchi, Kazuto Hatakeyama, Hikaru Tateishi, Yusuke Watanabe, Satoru Amano, Photoreaction of Graphene Oxide Nanosheets in Water Journal of Physical Chemistry C. ,vol. 115, pp. 19280- 19286 ,(2011) , 10.1021/JP206348S
Gopa Mishra, K. M. Parida, S. K. Singh, Facile Fabrication of S-TiO2/β-SiC Nanocomposite Photocatalyst for Hydrogen Evolution under Visible Light Irradiation ACS Sustainable Chemistry & Engineering. ,vol. 3, pp. 245- 253 ,(2015) , 10.1021/SC500570K
Min-Quan Yang, Yi-Jun Xu, Basic Principles for Observing the Photosensitizer Role of Graphene in the Graphene–Semiconductor Composite Photocatalyst from a Case Study on Graphene–ZnO Journal of Physical Chemistry C. ,vol. 117, pp. 21724- 21734 ,(2013) , 10.1021/JP408400C