Daisy-like Y(OH)3:Eu/Y2O3:Eu microstructure: Formation and luminescence properties

作者: Xue-Mei Zhang , Man-Lian Huang , Zhi-Jun Zhang , Bi-Qiu Liu , Jing-Tai Zhao

DOI: 10.1016/J.MATLET.2011.10.062

关键词:

摘要: Abstract An interesting daisy-like Y(OH)3:Eu microstructure was successfully prepared via a facile hydrothermal process employing potassium sodium tartrate (C4H4O6KNa) as structure-directing agent for the first time. Y2O3:Eu with same morphology obtained by calcining precursor at 800 °C 5 h. Phase and of products were investigated X-ray powder diffraction (XRD) scanning electron microscopy (SEM) respectively. It found that concentrations NaOH C4H4O6KNa played crucial roles in controlling particle size precursor. A possible formation mechanism novel proposed. The had stronger photoluminescence (PL) intensity than microrod reference nanoparticle.

参考文章(18)
Claudia Pacholski, Andreas Kornowski, Horst Weller, Self-Assembly of ZnO: From Nanodots to Nanorods Angewandte Chemie International Edition. ,vol. 41, pp. 1188- 1191 ,(2002) , 10.1002/1521-3773(20020402)41:7<1188::AID-ANIE1188>3.0.CO;2-5
M.K. Devaraju, Shu Yin, Tsugio Sato, Synthesis and characterization Y2O3:Eu3+ nanocrystals prepared via solvothermal refluxing route Materials Science and Engineering: C. ,vol. 29, pp. 1849- 1854 ,(2009) , 10.1016/J.MSEC.2009.02.022
David Zitoun, Nicola Pinna, Nathalie Frolet, Claude Belin, Single Crystal Manganese Oxide Multipods by Oriented Attachment Journal of the American Chemical Society. ,vol. 127, pp. 15034- 15035 ,(2005) , 10.1021/JA0555926
N. Joffin, J. Dexpert-Ghys, M. Verelst, G. Baret, A. Garcia, The influence of microstructure on luminescent properties of Y2O3:Eu prepared by spray pyrolysis Journal of Luminescence. ,vol. 113, pp. 249- 257 ,(2005) , 10.1016/J.JLUMIN.2004.10.021
Rui-Qi Song, Helmut Cölfen, Additive controlled crystallization CrystEngComm. ,vol. 13, pp. 1249- 1276 ,(2011) , 10.1039/C0CE00419G
Yuhua Zheng, Hongpeng You, Guang Jia, Kai Liu, Yanhua Song, Mei Yang, Yeju Huang, Hongjie Zhang, None, Facile synthesis of Y4O(OH)9NO3:Eu3+/Y2O3:Eu3+ nanotubes and nanobundles from nanolamellar precursors CrystEngComm. ,vol. 12, pp. 585- 590 ,(2010) , 10.1039/B912665A
Bing-Yue Tsui, Hsiao-Hsuan Hsu, Chun-Hu Cheng, High-Performance Metal–Insulator–Metal Capacitors With $\hbox{HfTiO}/\hbox{Y}_{2}\hbox{O}_{3}$ Stacked Dielectric IEEE Electron Device Letters. ,vol. 31, pp. 875- 877 ,(2010) , 10.1109/LED.2010.2051316
J. Polleux, N. Pinna, M. Antonietti, M. Niederberger, Ligand‐Directed Assembly of Preformed Titania Nanocrystals into Highly Anisotropic Nanostructures Advanced Materials. ,vol. 16, pp. 436- 439 ,(2004) , 10.1002/ADMA.200306251