Dilithium diphenylmethanediide; generation, redox relationship with lithium chlorodiphenylmethanide, implication with regard to aggregation

作者: Nicolaas J. R. van Eikema Hommes , Friedrich Bickelhaupt , Gerhard W. Klumpp

DOI: 10.1039/C39910000438

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摘要: Dilithium diphenylmethanediide, Ph2CLi2, prepared by reaction of dichlorodiphenylmethane with lithium p,p′-di-tert-butylbiphenyl, reacts organic halides and carbonyl compounds to give Chlorodiphenylmethanide, Ph2CLiCl, as a major product is assumed exist in two different states aggregation.

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