In Situ Transmission Electron Microscopy of Electric Field-Triggered Reversible Domain Formation in Bi-Based Lead-Free Piezoceramics

作者: Jens Kling , Xiaoli Tan , Wook Jo , Hans-Joachim Kleebe , Hartmut Fuess

DOI: 10.1111/J.1551-2916.2010.03778.X

关键词:

摘要: A lead-free piezoelectric 0.91(Bi1/2Na1/2)TiO3–0.06BaTiO3–0.03(K0.5Na0.5)NbO3 ceramic with high strain was examined in situ under an applied electric field using the transmission electron microscope. No domain structure is observed without field, but alternating leads to reversible formation of a lamellar structure. Correlations polarization and hysteresis loop measurements indicate field-induced phase transition from nonpolar ferroelectric state vice versa.

参考文章(26)
Shan-Tao Zhang, Alain Brice Kounga, Emil Aulbach, Helmut Ehrenberg, Jürgen Rödel, Giant strain in lead-free piezoceramics Bi0.5Na0.5TiO3–BaTiO3–K0.5Na0.5NbO3 system Applied Physics Letters. ,vol. 91, pp. 112906- ,(2007) , 10.1063/1.2783200
X. Tan, J. Frederick, C. Ma, E. Aulbach, M. Marsilius, W. Hong, T. Granzow, W. Jo, J. Rödel, Electric-field-induced antiferroelectric to ferroelectric phase transition in mechanically confined Pb0.99Nb0.02[(Zr0.57Sn0.43)0.94Ti0.06]0.98O3 Physical Review B. ,vol. 81, pp. 014103- ,(2010) , 10.1103/PHYSREVB.81.014103
Wenwei Ge, Hu Cao, Jiefang Li, D. Viehland, Qinhui Zhang, Haosu Luo, Influence of dc-bias on phase stability in Mn-doped Na0.5Bi0.5TiO3-5.6 at. %BaTiO3 single crystals Applied Physics Letters. ,vol. 95, pp. 162903- ,(2009) , 10.1063/1.3253412
Haixia Wang, Haiqing Xu, Haosu Luo, Zhiwen Yin, A. A. Bokov, Z.-G. Ye, Dielectric anomalies of the relaxor-based 0.9Pb(Mg1∕3Nb2∕3)O3‐0.1PbTiO3 single crystals Applied Physics Letters. ,vol. 87, pp. 012904- ,(2005) , 10.1063/1.1990253
Wook Jo, Torsten Granzow, Emil Aulbach, Jürgen Rödel, Dragan Damjanovic, Origin of the large strain response in (K0.5Na0.5)NbO3-modified (Bi0.5Na0.5)TiO3―BaTiO3 lead-free piezoceramics Journal of Applied Physics. ,vol. 105, pp. 094102- ,(2009) , 10.1063/1.3121203
G. O. Jones, P. A. Thomas, The tetragonal phase of Na0.5Bi0.5TiO3 – a new variant of the perovskite structure Acta Crystallographica Section B-structural Science. ,vol. 56, pp. 426- 430 ,(2000) , 10.1107/S0108768100001166
Maxim I. Morozov, Dragan Damjanovic, Hardening-softening transition in Fe-doped Pb(Zr,Ti)O3 ceramics and evolution of the third harmonic of the polarization response Journal of Applied Physics. ,vol. 104, pp. 034107- ,(2008) , 10.1063/1.2963704
Xunhu Dai, Z. Xu, Dwight Viehland, The spontaneous relaxor to normal ferroelectric transformation in La-modified lead zirconate titanate Philosophical Magazine Part B. ,vol. 70, pp. 33- 48 ,(1994) , 10.1080/01418639408240192