ESR and Magnetic Investigation of Lithium Intercalated VSe2
作者： Y. Watanabe
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摘要: X-band ESR spectra are examined during the Li intercalation process of VSe2 in n-butyllithium solution. The formation V2+ ions at an early stage reaction and their subsequent partial disappearance ascertained case solutions where contents totally deficient for production Li2VSe2. temperature-dependence width lines exhibits a broad minimum around 150 K. This is interpreted terms effects interaction with other vanadium some different valence states. X-Band-ESR-Spektren werden wahrend des Li-Einlagerungs-Prozesses von n-Butylli-thium-Losung untersucht. Die Bildung V2+-Ionen im fruhen Stadium der Reaktion und nachfolgende teilweise Zerfall Falle einer Losung, gesamte Li-Gehalt nicht fur die Li2 ausreicht, bestatigt. Temperatur-Abhangigkeit Linienbreite V2+-ESR zeigt ein flaches Minimum um Dieses wird mit Wechselwirkungen zwischen den Vanadium-Ionen anderen Valenz-Zustanden interpretiert.
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